Synthesis and characterisation of the first E-unidentate [Ph2P(O)NP(E)Ph-2]- metal complexes [Au{Ph2P(O)NP(E)Ph2-E}{Ph2P(O)NHPPh2}] and [Pd{Ph2P(O)NP(E)Ph2-E}2(H2NCH2CH2NH2)] (E = S or Se)

A M Z  Slawin; M B  Smith; J D  Woollins

doi:10.1039/a801856a

Synthesis and characterisation of the first E-unidentate [Ph₂P(O)NP(E)Ph-₂]- metal complexes [Au{Ph₂P(O)NP(E)Ph₂-E}{Ph₂P(O)NHPPh₂}] and [Pd{Ph₂P(O)NP(E)Ph₂-E}₂(H₂NCH₂CH₂NH₂)] (E = S or Se)

A M Z Slawin
, M B Smith
, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Chloride metathesis of[AuCl(HL)] [HL = Ph2P(O)NHPPh2] or [PdCl2(en)] (en = ethane-1,2-diamine) in CH3OH with either 1 (or 2) equivalents of [Ph2P(O)NP(E)Ph-2](-) (E = S or Se) gave the neutral compounds [Au{Ph2P(O)NP(E)Ph-2-E}(HL)] or [Pd{Ph2P(O)NP(E)Ph-2-E}(2)(en)] respectively; the anionic ligands in these complexes adopt a new bonding mode and furthermore are involved in intramolecular N-H ... OP hydrogen bonding with HL or en.

Original language	English
Pages (from-to)	1537-1539
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/a801856a
Publication status	Published - 21 May 1998

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@article{528b873755434d47a80cf5cb07c86d7e,

title = "Synthesis and characterisation of the first E-unidentate [Ph2P(O)NP(E)Ph-2]- metal complexes [Au\{Ph2P(O)NP(E)Ph2-E\}\{Ph2P(O)NHPPh2\}] and [Pd\{Ph2P(O)NP(E)Ph2-E\}2(H2NCH2CH2NH2)] (E = S or Se)",

abstract = "Chloride metathesis of[AuCl(HL)] [HL = Ph2P(O)NHPPh2] or [PdCl2(en)] (en = ethane-1,2-diamine) in CH3OH with either 1 (or 2) equivalents of [Ph2P(O)NP(E)Ph-2](-) (E = S or Se) gave the neutral compounds [Au\{Ph2P(O)NP(E)Ph-2-E\}(HL)] or [Pd\{Ph2P(O)NP(E)Ph-2-E\}(2)(en)] respectively; the anionic ligands in these complexes adopt a new bonding mode and furthermore are involved in intramolecular N-H ... OP hydrogen bonding with HL or en.",

author = "Slawin, \{A M Z\} and Smith, \{M B\} and Woollins, \{J D\}",

year = "1998",

month = may,

day = "21",

doi = "10.1039/a801856a",

language = "English",

pages = "1537--1539",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "10",

}

Synthesis and characterisation of the first E-unidentate [Ph₂P(O)NP(E)Ph-₂]- metal complexes [Au{Ph₂P(O)NP(E)Ph₂-E}{Ph₂P(O)NHPPh₂}] and [Pd{Ph₂P(O)NP(E)Ph₂-E}₂(H₂NCH₂CH₂NH₂)] (E = S or Se). / Slawin, A M Z ; Smith, M B ; Woollins, J D .
In: Journal of the Chemical Society, Dalton Transactions, No. 10, 21.05.1998, p. 1537-1539.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and characterisation of the first E-unidentate [Ph2P(O)NP(E)Ph-2]- metal complexes [Au{Ph2P(O)NP(E)Ph2-E}{Ph2P(O)NHPPh2}] and [Pd{Ph2P(O)NP(E)Ph2-E}2(H2NCH2CH2NH2)] (E = S or Se)

AU - Slawin, A M Z

AU - Smith, M B

AU - Woollins, J D

PY - 1998/5/21

Y1 - 1998/5/21

N2 - Chloride metathesis of[AuCl(HL)] [HL = Ph2P(O)NHPPh2] or [PdCl2(en)] (en = ethane-1,2-diamine) in CH3OH with either 1 (or 2) equivalents of [Ph2P(O)NP(E)Ph-2](-) (E = S or Se) gave the neutral compounds [Au{Ph2P(O)NP(E)Ph-2-E}(HL)] or [Pd{Ph2P(O)NP(E)Ph-2-E}(2)(en)] respectively; the anionic ligands in these complexes adopt a new bonding mode and furthermore are involved in intramolecular N-H ... OP hydrogen bonding with HL or en.

AB - Chloride metathesis of[AuCl(HL)] [HL = Ph2P(O)NHPPh2] or [PdCl2(en)] (en = ethane-1,2-diamine) in CH3OH with either 1 (or 2) equivalents of [Ph2P(O)NP(E)Ph-2](-) (E = S or Se) gave the neutral compounds [Au{Ph2P(O)NP(E)Ph-2-E}(HL)] or [Pd{Ph2P(O)NP(E)Ph-2-E}(2)(en)] respectively; the anionic ligands in these complexes adopt a new bonding mode and furthermore are involved in intramolecular N-H ... OP hydrogen bonding with HL or en.

U2 - 10.1039/a801856a

DO - 10.1039/a801856a

M3 - Article

SN - 0300-9246

SP - 1537

EP - 1539

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 10