Synthesis and characterisation of four- and six-membered P–Se heterocycles

Sahrah Parveen, Petr Kilian, Alexandra M.Z. Slawin, J. Derek Woollins*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The preparation, spectroscopic characterisation and crystal structures of [FcP(µ-Se)Se]2, [FcP(µ-Se2)Se]2and [PhP(µ-Se2)Se]2are reported. Crystallographic data reveal planar four-membered PSePSe and skewed six-membered P2Se4rings, respectively, in all cases with trans arrangement of organic substituents and exo selenium atoms. Whilst stable at room temperature in solid state, NMR data suggest the six-membered rings of both the ferrocenyl and phenyl compounds decompose in the solution with loss of red selenium, forming PSe2PSe five-membered rings.

Original languageEnglish
Pages (from-to)2586-2590
Number of pages5
JournalDalton Transactions
Issue number21
Early online date8 Mar 2006
DOIs
Publication statusPublished - 2006

Keywords

  • Phosphorus-selenium heterocycles
  • Cyclopolyphosphines
  • Reagents

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