Synthesis and characterisation of Au(I)-(ITent) complexes

S.R. Patrick; A. Collado; S. Meiries; A.M.Z. Slawin; S.P. Nolan

doi:10.1016/j.jorganchem.2014.04.022

Synthesis and characterisation of Au(I)-(ITent) complexes

S.R. Patrick, A. Collado, S. Meiries, A.M.Z. Slawin, S.P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of novel [AuCl(ITent)] and [Au(OH)(ITent)] complexes is reported. They have been fully characterised and their steric parameters were assessed by calculating percent buried volumes and producing steric maps from their crystal structures in the solid state.

Original language	English
Pages (from-to)	152–154
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	775
Early online date	5 May 2014
DOIs	https://doi.org/10.1016/j.jorganchem.2014.04.022
Publication status	Published - 1 Jan 2015

Keywords

Gold
N-Heterocyclic carbene
Synthesis
Sterics

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10.1016/j.jorganchem.2014.04.022

Nolan_2014_JOC_AuITent_AM
Copyright © 2014 Published by Elsevier B.V. NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, 775, 2015, doi: 10.1016/j.jorganchem.2014.04.022
Accepted author manuscript, 562 KB

Cite this

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title = "Synthesis and characterisation of Au(I)-(ITent) complexes",

abstract = "The synthesis of novel [AuCl(ITent)] and [Au(OH)(ITent)] complexes is reported. They have been fully characterised and their steric parameters were assessed by calculating percent buried volumes and producing steric maps from their crystal structures in the solid state.",

keywords = "Gold, N-Heterocyclic carbene, Synthesis, Sterics",

author = "S.R. Patrick and A. Collado and S. Meiries and A.M.Z. Slawin and S.P. Nolan",

note = "The ERC (Advanced Investigator Award-FUNCAT), the EPSRC and Syngenta are gratefully acknowledged for support of this work. Umicore AG is acknowledged for their generous gift of auric acid. S.P.N. is a Royal Society Wolfson Research Merit Award holder. ",

year = "2015",

month = jan,

day = "1",

doi = "10.1016/j.jorganchem.2014.04.022",

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journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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T1 - Synthesis and characterisation of Au(I)-(ITent) complexes

AU - Patrick, S.R.

AU - Collado, A.

AU - Meiries, S.

AU - Slawin, A.M.Z.

AU - Nolan, S.P.

N1 - The ERC (Advanced Investigator Award-FUNCAT), the EPSRC and Syngenta are gratefully acknowledged for support of this work. Umicore AG is acknowledged for their generous gift of auric acid. S.P.N. is a Royal Society Wolfson Research Merit Award holder.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - The synthesis of novel [AuCl(ITent)] and [Au(OH)(ITent)] complexes is reported. They have been fully characterised and their steric parameters were assessed by calculating percent buried volumes and producing steric maps from their crystal structures in the solid state.

AB - The synthesis of novel [AuCl(ITent)] and [Au(OH)(ITent)] complexes is reported. They have been fully characterised and their steric parameters were assessed by calculating percent buried volumes and producing steric maps from their crystal structures in the solid state.

KW - Gold

KW - N-Heterocyclic carbene

KW - Synthesis

KW - Sterics

UR - http://www.sciencedirect.com/science/article/pii/S0022328X14002046#appd001

UR - http://www.sciencedirect.com/science/article/pii/S0022328X14002046#appd002

U2 - 10.1016/j.jorganchem.2014.04.022

DO - 10.1016/j.jorganchem.2014.04.022

M3 - Article

SN - 0022-328X

VL - 775

SP - 152

EP - 154

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Synthesis and characterisation of Au(I)-(ITent) complexes

Abstract

Keywords

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FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis