Symmetric and asymmetric 13-vertex bimetallacarboranes by polyhedral expansion

Maria Elena Lopez; Michael J. Edie; David Ellis; Anke Horneber; Stuart A. Macgregor; Georgina M. Rosair; Alan J. Welch

doi:10.1039/b703822d

Symmetric and asymmetric 13-vertex bimetallacarboranes by polyhedral expansion

Maria Elena Lopez
, Michael J. Edie
, David Ellis
, Anke Horneber
, Stuart A. Macgregor
, Georgina M. Rosair
, Alan J. Welch^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Symmetric 4,5,2,3-M₂C₂B₉ 13-vertex bimetallacarboranes of cobalt and ruthenium with 14 skeletal electron pairs are afforded by reduction and metallation of 3,1,2-MC₂B₉ icosahedra; the symmetric species can be converted to their asymmetric 4,5,1,6-M₂C₂B₉ isomers by heat, but an easier route is by thermolysis of the reduced species before metallation.

Original language	English
Pages (from-to)	2243-2245
Number of pages	3
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/b703822d
Publication status	Published - 2007

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title = "Symmetric and asymmetric 13-vertex bimetallacarboranes by polyhedral expansion",

abstract = "Symmetric 4,5,2,3-M2C2B9 13-vertex bimetallacarboranes of cobalt and ruthenium with 14 skeletal electron pairs are afforded by reduction and metallation of 3,1,2-MC2B9 icosahedra; the symmetric species can be converted to their asymmetric 4,5,1,6-M2C2B9 isomers by heat, but an easier route is by thermolysis of the reduced species before metallation.",

author = "Lopez, \{Maria Elena\} and Edie, \{Michael J.\} and David Ellis and Anke Horneber and Macgregor, \{Stuart A.\} and Rosair, \{Georgina M.\} and Welch, \{Alan J.\}",

year = "2007",

doi = "10.1039/b703822d",

language = "English",

pages = "2243--2245",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "22",

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TY - JOUR

T1 - Symmetric and asymmetric 13-vertex bimetallacarboranes by polyhedral expansion

AU - Lopez, Maria Elena

AU - Edie, Michael J.

AU - Ellis, David

AU - Horneber, Anke

AU - Macgregor, Stuart A.

AU - Rosair, Georgina M.

AU - Welch, Alan J.

PY - 2007

Y1 - 2007

N2 - Symmetric 4,5,2,3-M2C2B9 13-vertex bimetallacarboranes of cobalt and ruthenium with 14 skeletal electron pairs are afforded by reduction and metallation of 3,1,2-MC2B9 icosahedra; the symmetric species can be converted to their asymmetric 4,5,1,6-M2C2B9 isomers by heat, but an easier route is by thermolysis of the reduced species before metallation.

AB - Symmetric 4,5,2,3-M2C2B9 13-vertex bimetallacarboranes of cobalt and ruthenium with 14 skeletal electron pairs are afforded by reduction and metallation of 3,1,2-MC2B9 icosahedra; the symmetric species can be converted to their asymmetric 4,5,1,6-M2C2B9 isomers by heat, but an easier route is by thermolysis of the reduced species before metallation.

UR - https://www.scopus.com/pages/publications/34249823956

U2 - 10.1039/b703822d

DO - 10.1039/b703822d

M3 - Article

AN - SCOPUS:34249823956

SN - 1359-7345

SP - 2243

EP - 2245

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Symmetric and asymmetric 13-vertex bimetallacarboranes by polyhedral expansion

Abstract

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