Supported ionic liquid phase catalysis with supercritical flow

Ulrich Hintermair; Guoying Zhao; Catherine C. Santini; Mark J. Muldoon; David J. Cole-Hamilton

doi:10.1039/b616186c

Supported ionic liquid phase catalysis with supercritical flow

Ulrich Hintermair, Guoying Zhao, Catherine C. Santini, Mark J. Muldoon, David J. Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

Rapid hydroformylation of 1-octene (rates up to 800 h(-1)) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO(2)) over a fixed bed supported ionic liquid phase catalyst.

Original language	English
Pages (from-to)	1462-1464
Number of pages	3
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b616186c
Publication status	Published - 2007

Keywords

HOMOGENEOUS CATALYSIS
PHOSPHINE CATALYSTS
CARBON-DIOXIDE
SILP CATALYSIS
HYDROFORMYLATION
PROPENE

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title = "Supported ionic liquid phase catalysis with supercritical flow",

abstract = "Rapid hydroformylation of 1-octene (rates up to 800 h(-1)) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO(2)) over a fixed bed supported ionic liquid phase catalyst.",

keywords = "HOMOGENEOUS CATALYSIS, PHOSPHINE CATALYSTS, CARBON-DIOXIDE, SILP CATALYSIS, HYDROFORMYLATION, PROPENE",

author = "Ulrich Hintermair and Guoying Zhao and Santini, \{Catherine C.\} and Muldoon, \{Mark J.\} and Cole-Hamilton, \{David J.\}",

year = "2007",

doi = "10.1039/b616186c",

language = "English",

pages = "1462--1464",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "14",

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TY - JOUR

T1 - Supported ionic liquid phase catalysis with supercritical flow

AU - Hintermair, Ulrich

AU - Zhao, Guoying

AU - Santini, Catherine C.

AU - Muldoon, Mark J.

AU - Cole-Hamilton, David J.

PY - 2007

Y1 - 2007

N2 - Rapid hydroformylation of 1-octene (rates up to 800 h(-1)) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO(2)) over a fixed bed supported ionic liquid phase catalyst.

AB - Rapid hydroformylation of 1-octene (rates up to 800 h(-1)) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO(2)) over a fixed bed supported ionic liquid phase catalyst.

KW - HOMOGENEOUS CATALYSIS

KW - PHOSPHINE CATALYSTS

KW - CARBON-DIOXIDE

KW - SILP CATALYSIS

KW - HYDROFORMYLATION

KW - PROPENE

UR - https://www.scopus.com/pages/publications/33947689797

UR - http://www.rsc.org/ej/CC/2007/b616186c.pdf

U2 - 10.1039/b616186c

DO - 10.1039/b616186c

M3 - Article

SN - 1359-7345

SP - 1462

EP - 1464

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Supported ionic liquid phase catalysis with supercritical flow

Abstract

Keywords

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