Supported ionic liquid phase catalysis with supercritical flow

Ulrich Hintermair, Guoying Zhao, Catherine C. Santini, Mark J. Muldoon, David J. Cole-Hamilton

Research output: Contribution to journalArticlepeer-review

85 Citations (Scopus)

Abstract

Rapid hydroformylation of 1-octene (rates up to 800 h(-1)) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO(2)) over a fixed bed supported ionic liquid phase catalyst.

Original languageEnglish
Pages (from-to)1462-1464
Number of pages3
JournalChemical Communications
Issue number14
DOIs
Publication statusPublished - 2007

Keywords

  • HOMOGENEOUS CATALYSIS
  • PHOSPHINE CATALYSTS
  • CARBON-DIOXIDE
  • SILP CATALYSIS
  • HYDROFORMYLATION
  • PROPENE

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