SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

A  IBBOTSON; A M Z  SLAWIN; S E  THOMAS; G J  TUSTIN; D J  WILLIAMS

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

A IBBOTSON
, A M Z SLAWIN
, S E THOMAS
, G J TUSTIN
, D J WILLIAMS

Research output: Contribution to journal › Article › peer-review

Abstract

The sulphonyl and sulphinyl substituted oxadienes [RS(O)(n)CH = CHC(Me) = O; R = Bu(t), Ph; n = 2,1] form stable tricarbonyliron(0) complexes; the sulphinyl complexes formed are diastereoisomerically pure and the relative stereochemistry of the tricarbonyliron(0) unit and the sulphinyl substituent in the products has been determined by an X-ray crystal structure analysis of [Bu(t)S(O)CH = CHC(Me) = O](CO)3Fe0.

Original language	English
Pages (from-to)	1534-1536
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
Publication status	Published - 1 Nov 1991

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title = "SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES",

abstract = "The sulphonyl and sulphinyl substituted oxadienes [RS(O)(n)CH = CHC(Me) = O; R = Bu(t), Ph; n = 2,1] form stable tricarbonyliron(0) complexes; the sulphinyl complexes formed are diastereoisomerically pure and the relative stereochemistry of the tricarbonyliron(0) unit and the sulphinyl substituent in the products has been determined by an X-ray crystal structure analysis of [Bu(t)S(O)CH = CHC(Me) = O](CO)3Fe0.",

keywords = "KETONES",

author = "A IBBOTSON and SLAWIN, \{A M Z\} and THOMAS, \{S E\} and TUSTIN, \{G J\} and WILLIAMS, \{D J\}",

year = "1991",

month = nov,

day = "1",

language = "English",

pages = "1534--1536",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "21",

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TY - JOUR

T1 - SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

AU - IBBOTSON, A

AU - SLAWIN, A M Z

AU - THOMAS, S E

AU - TUSTIN, G J

AU - WILLIAMS, D J

PY - 1991/11/1

Y1 - 1991/11/1

N2 - The sulphonyl and sulphinyl substituted oxadienes [RS(O)(n)CH = CHC(Me) = O; R = Bu(t), Ph; n = 2,1] form stable tricarbonyliron(0) complexes; the sulphinyl complexes formed are diastereoisomerically pure and the relative stereochemistry of the tricarbonyliron(0) unit and the sulphinyl substituent in the products has been determined by an X-ray crystal structure analysis of [Bu(t)S(O)CH = CHC(Me) = O](CO)3Fe0.

AB - The sulphonyl and sulphinyl substituted oxadienes [RS(O)(n)CH = CHC(Me) = O; R = Bu(t), Ph; n = 2,1] form stable tricarbonyliron(0) complexes; the sulphinyl complexes formed are diastereoisomerically pure and the relative stereochemistry of the tricarbonyliron(0) unit and the sulphinyl substituent in the products has been determined by an X-ray crystal structure analysis of [Bu(t)S(O)CH = CHC(Me) = O](CO)3Fe0.

KW - KETONES

M3 - Article

SN - 0022-4936

SP - 1534

EP - 1536

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 21

ER -

SULFINYL-CONTROLLED FORMATION OF DIASTEREOISOMERICALLY PURE (OXADIENE)TRICARBONYLIRON(0) COMPLEXES

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