Substitution reactions of fluorinated triarylmethanols in formic acid

Adrian F. Andrews; Brigitte M.J. Vandenbulcke; John C. Walton

doi:10.1039/C39780000389

Substitution reactions of fluorinated triarylmethanols in formic acid

Adrian F. Andrews, Brigitte M.J. Vandenbulcke, John C. Walton^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction with formic acid of triarylmethanols containing para-fluorine substituents gives, in addition to the expected triarylmethanes, products in which one fluorine has been replaced by a hydroxy-group; in contrast, pentafluorophenyldiphenylmethanol on similar treatment gives the pentafluorophenyldiphenylmethane together 9-(pentafluorophenyl)-fluorene.

Original language	English
Pages (from-to)	389-391
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/C39780000389
Publication status	Published - 1 Jan 1978

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title = "Substitution reactions of fluorinated triarylmethanols in formic acid",

abstract = "Reaction with formic acid of triarylmethanols containing para-fluorine substituents gives, in addition to the expected triarylmethanes, products in which one fluorine has been replaced by a hydroxy-group; in contrast, pentafluorophenyldiphenylmethanol on similar treatment gives the pentafluorophenyldiphenylmethane together 9-(pentafluorophenyl)-fluorene.",

author = "Andrews, \{Adrian F.\} and Vandenbulcke, \{Brigitte M.J.\} and Walton, \{John C.\}",

year = "1978",

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doi = "10.1039/C39780000389",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Andrews, Adrian F.

AU - Vandenbulcke, Brigitte M.J.

AU - Walton, John C.

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Y1 - 1978/1/1

N2 - Reaction with formic acid of triarylmethanols containing para-fluorine substituents gives, in addition to the expected triarylmethanes, products in which one fluorine has been replaced by a hydroxy-group; in contrast, pentafluorophenyldiphenylmethanol on similar treatment gives the pentafluorophenyldiphenylmethane together 9-(pentafluorophenyl)-fluorene.

AB - Reaction with formic acid of triarylmethanols containing para-fluorine substituents gives, in addition to the expected triarylmethanes, products in which one fluorine has been replaced by a hydroxy-group; in contrast, pentafluorophenyldiphenylmethanol on similar treatment gives the pentafluorophenyldiphenylmethane together 9-(pentafluorophenyl)-fluorene.

UR - https://www.scopus.com/pages/publications/37049098126

U2 - 10.1039/C39780000389

DO - 10.1039/C39780000389

M3 - Article

AN - SCOPUS:37049098126

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EP - 391

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 9

ER -

Substitution reactions of fluorinated triarylmethanols in formic acid

Abstract

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