Substitution of transition metals into azamacrocycle-gallophosphate inorganic-organic hybrid materials

D Wragg; Russell Edward Morris

Substitution of transition metals into azamacrocycle-gallophosphate inorganic-organic hybrid materials

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Abstract

Transition metals (Cu, Mn and Co) have been substituted for gallium in an azamacrocycle-containing gallium phosphate inorganic-organic hybrid material (GaPO4)(2)(OH)F-2. Ga(C10N4H24). The substitution of the gallium by copper and manganese occurs at the octahedral site that is at the centre of the azamacrocycle complex. The effect of this substitution on the structure of the materials has been studied using Rietveld refinement against synchrotron X-ray powder diffraction data and electron spin resonance spectroscopy.

Original language	English
Pages (from-to)	513-517
Number of pages	5
Journal	Journal of Materials Chemistry
Volume	11
Publication status	Published - 2001

Keywords

STRUCTURAL CHARACTERIZATION
DIFFRACTION
PHOSPHATES
FRAMEWORK
TEMPLATE

Cite this

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title = "Substitution of transition metals into azamacrocycle-gallophosphate inorganic-organic hybrid materials",

abstract = "Transition metals (Cu, Mn and Co) have been substituted for gallium in an azamacrocycle-containing gallium phosphate inorganic-organic hybrid material (GaPO4)(2)(OH)F-2. Ga(C10N4H24). The substitution of the gallium by copper and manganese occurs at the octahedral site that is at the centre of the azamacrocycle complex. The effect of this substitution on the structure of the materials has been studied using Rietveld refinement against synchrotron X-ray powder diffraction data and electron spin resonance spectroscopy.",

keywords = "STRUCTURAL CHARACTERIZATION, DIFFRACTION, PHOSPHATES, FRAMEWORK, TEMPLATE",

author = "D Wragg and Morris, {Russell Edward}",

year = "2001",

language = "English",

volume = "11",

pages = "513--517",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

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T1 - Substitution of transition metals into azamacrocycle-gallophosphate inorganic-organic hybrid materials

AU - Wragg, D

AU - Morris, Russell Edward

PY - 2001

Y1 - 2001

N2 - Transition metals (Cu, Mn and Co) have been substituted for gallium in an azamacrocycle-containing gallium phosphate inorganic-organic hybrid material (GaPO4)(2)(OH)F-2. Ga(C10N4H24). The substitution of the gallium by copper and manganese occurs at the octahedral site that is at the centre of the azamacrocycle complex. The effect of this substitution on the structure of the materials has been studied using Rietveld refinement against synchrotron X-ray powder diffraction data and electron spin resonance spectroscopy.

AB - Transition metals (Cu, Mn and Co) have been substituted for gallium in an azamacrocycle-containing gallium phosphate inorganic-organic hybrid material (GaPO4)(2)(OH)F-2. Ga(C10N4H24). The substitution of the gallium by copper and manganese occurs at the octahedral site that is at the centre of the azamacrocycle complex. The effect of this substitution on the structure of the materials has been studied using Rietveld refinement against synchrotron X-ray powder diffraction data and electron spin resonance spectroscopy.

KW - STRUCTURAL CHARACTERIZATION

KW - DIFFRACTION

KW - PHOSPHATES

KW - FRAMEWORK

KW - TEMPLATE

UR - http://www.scopus.com/inward/record.url?scp=0035120387&partnerID=8YFLogxK

M3 - Article

SN - 0959-9428

VL - 11

SP - 513

EP - 517

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

ER -

Substitution of transition metals into azamacrocycle-gallophosphate inorganic-organic hybrid materials

Abstract

Keywords

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