Abstract
An advanced ring-closing metathesis precursor for the synthesis of the marine macrolide neopeltolide is prepared in a stereocontrolled manner by the coupling of the C2–C10 and C11–C16 subunits. The metathesis reaction of 4 with Grubbs’ II or Nolan’s indenylidene catalyst led to the unexpected formation of cycloheptene 18.
| Original language | English |
|---|---|
| Pages (from-to) | 5761-5763 |
| Number of pages | 3 |
| Journal | Tetrahedron Letters |
| Volume | 51 |
| Issue number | 44 |
| Early online date | 7 Sept 2010 |
| DOIs | |
| Publication status | Published - 3 Nov 2010 |
UN SDGs
This output contributes to the following UN Sustainable Development Goals (SDGs)
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SDG 14 Life Below Water
Fingerprint
Dive into the research topics of 'Studies towards the synthesis of neopeltolide: synthesis of a ring closing metathesis macrocyclization precursor'. Together they form a unique fingerprint.Projects
- 1 Finished
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RS Uni Research Fellowship Renewal 2010: University Research Fellowship - New Methods and Strategies for the Synthesis of Bioactive Natural Products
Florence, G. (PI)
1/10/10 → 30/09/13
Project: Fellowship
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