Studies of model zeolitic catalysts: determination of the site of adsorption of methyl chloride sorbed in zeolite rho by powder x-ray diffraction

Ian Gameson; Trevor Rayment; John M. Thomas; Paul A. Wright

doi:10.1021/j100315a026

Studies of model zeolitic catalysts: determination of the site of adsorption of methyl chloride sorbed in zeolite rho by powder x-ray diffraction

Ian Gameson^*, Trevor Rayment, John M. Thomas, Paul A. Wright

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The location of methyl chloride sorbed within zeolite rho has been determined by Rietveld profile analysis of powder X-ray diffraction data in the temperature range 40-250K. The methyl group is situated close to the center of an octagonal prism with the chlorine atom at the center of the octagonal face of the alpha -cage. This position is similar to that found previously for xenon and krypton sorbed in zeolite rho.

Original language	English
Pages (from-to)	988-991
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	92
Issue number	4
DOIs	https://doi.org/10.1021/j100315a026
Publication status	Published - 1 Jan 1988

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title = "Studies of model zeolitic catalysts: determination of the site of adsorption of methyl chloride sorbed in zeolite rho by powder x-ray diffraction",

abstract = "The location of methyl chloride sorbed within zeolite rho has been determined by Rietveld profile analysis of powder X-ray diffraction data in the temperature range 40-250K. The methyl group is situated close to the center of an octagonal prism with the chlorine atom at the center of the octagonal face of the alpha -cage. This position is similar to that found previously for xenon and krypton sorbed in zeolite rho.",

author = "Ian Gameson and Trevor Rayment and Thomas, {John M.} and Wright, {Paul A.}",

year = "1988",

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T2 - determination of the site of adsorption of methyl chloride sorbed in zeolite rho by powder x-ray diffraction

AU - Gameson, Ian

AU - Rayment, Trevor

AU - Thomas, John M.

AU - Wright, Paul A.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - The location of methyl chloride sorbed within zeolite rho has been determined by Rietveld profile analysis of powder X-ray diffraction data in the temperature range 40-250K. The methyl group is situated close to the center of an octagonal prism with the chlorine atom at the center of the octagonal face of the alpha -cage. This position is similar to that found previously for xenon and krypton sorbed in zeolite rho.

AB - The location of methyl chloride sorbed within zeolite rho has been determined by Rietveld profile analysis of powder X-ray diffraction data in the temperature range 40-250K. The methyl group is situated close to the center of an octagonal prism with the chlorine atom at the center of the octagonal face of the alpha -cage. This position is similar to that found previously for xenon and krypton sorbed in zeolite rho.

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DO - 10.1021/j100315a026

M3 - Article

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SN - 0022-3654

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Studies of model zeolitic catalysts: determination of the site of adsorption of methyl chloride sorbed in zeolite rho by powder x-ray diffraction

Abstract

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