Structure-Property Relationships in Polynuclear mu-O Bridged Aqua Clusters: Effect of M-muO bond covalency

David Trevor Richens

doi:10.1080/02603590500403875

Structure-Property Relationships in Polynuclear mu-O Bridged Aqua Clusters: Effect of M-muO bond covalency

David Trevor Richens

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The extent of M-mu O bond covalency is the dominant factor controlling the M-mu O distance, the terminal water pK(a) and exchange mechanism within a range of polynuclear oxo-bridged aqueous clusters. These effects lead to limiting associative/dissociative mechanisms for water exchange on the polynuclear species.

Original language	English
Pages (from-to)	217-232
Number of pages	16
Journal	Comments on Inorganic Chemistry
Volume	26
DOIs	https://doi.org/10.1080/02603590500403875
Publication status	Published - 2005

Keywords

oxo-bridged clusters
170 NMR
water exchange mechanism
M-O covalency
correlation
RAY CRYSTAL-STRUCTURE
X-RAY
WATER EXCHANGE
O-17 NMR
AQUEOUS-SOLUTION
SINGLE BONDS
METAL-IONS
COMPLEX
MOLYBDENUM(IV)
TUNGSTEN(IV)

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10.1080/02603590500403875

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title = "Structure-Property Relationships in Polynuclear mu-O Bridged Aqua Clusters: Effect of M-muO bond covalency",

abstract = "The extent of M-mu O bond covalency is the dominant factor controlling the M-mu O distance, the terminal water pK(a) and exchange mechanism within a range of polynuclear oxo-bridged aqueous clusters. These effects lead to limiting associative/dissociative mechanisms for water exchange on the polynuclear species.",

keywords = "oxo-bridged clusters, 170 NMR, water exchange mechanism, M-O covalency, correlation, RAY CRYSTAL-STRUCTURE, X-RAY, WATER EXCHANGE, O-17 NMR, AQUEOUS-SOLUTION, SINGLE BONDS, METAL-IONS, COMPLEX, MOLYBDENUM(IV), TUNGSTEN(IV)",

author = "Richens, {David Trevor}",

year = "2005",

doi = "10.1080/02603590500403875",

language = "English",

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pages = "217--232",

journal = "Comments on Inorganic Chemistry",

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N2 - The extent of M-mu O bond covalency is the dominant factor controlling the M-mu O distance, the terminal water pK(a) and exchange mechanism within a range of polynuclear oxo-bridged aqueous clusters. These effects lead to limiting associative/dissociative mechanisms for water exchange on the polynuclear species.

AB - The extent of M-mu O bond covalency is the dominant factor controlling the M-mu O distance, the terminal water pK(a) and exchange mechanism within a range of polynuclear oxo-bridged aqueous clusters. These effects lead to limiting associative/dissociative mechanisms for water exchange on the polynuclear species.

KW - oxo-bridged clusters

KW - 170 NMR

KW - water exchange mechanism

KW - M-O covalency

KW - correlation

KW - RAY CRYSTAL-STRUCTURE

KW - X-RAY

KW - WATER EXCHANGE

KW - O-17 NMR

KW - AQUEOUS-SOLUTION

KW - SINGLE BONDS

KW - METAL-IONS

KW - COMPLEX

KW - MOLYBDENUM(IV)

KW - TUNGSTEN(IV)

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DO - 10.1080/02603590500403875

M3 - Article

SN - 0260-3594

VL - 26

SP - 217

EP - 232

JO - Comments on Inorganic Chemistry

JF - Comments on Inorganic Chemistry

ER -

Structure-Property Relationships in Polynuclear mu-O Bridged Aqua Clusters: Effect of M-muO bond covalency

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Keywords

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