Structure-Property Relationships in Polynuclear mu-O Bridged Aqua Clusters: Effect of M-muO bond covalency

David Trevor Richens

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The extent of M-mu O bond covalency is the dominant factor controlling the M-mu O distance, the terminal water pK(a) and exchange mechanism within a range of polynuclear oxo-bridged aqueous clusters. These effects lead to limiting associative/dissociative mechanisms for water exchange on the polynuclear species.

Original languageEnglish
Pages (from-to)217-232
Number of pages16
JournalComments on Inorganic Chemistry
Volume26
DOIs
Publication statusPublished - 2005

Keywords

  • oxo-bridged clusters
  • 170 NMR
  • water exchange mechanism
  • M-O covalency
  • correlation
  • RAY CRYSTAL-STRUCTURE
  • X-RAY
  • WATER EXCHANGE
  • O-17 NMR
  • AQUEOUS-SOLUTION
  • SINGLE BONDS
  • METAL-IONS
  • COMPLEX
  • MOLYBDENUM(IV)
  • TUNGSTEN(IV)

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