Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework

Craig M. Brown; Anibal Javier Ramirez-Cuesta; Jae-Hyuk Her; Paul S. Wheatley; Russell E. Morris

doi:10.1016/j.chemphys.2013.08.010

Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework

Craig M. Brown^*, Anibal Javier Ramirez-Cuesta, Jae-Hyuk Her, Paul S. Wheatley, Russell E. Morris

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The structure of Ni-2(dobdc) (dobdc(4) = 2,5-dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogs and the Ni2+ variant shows the shortest deuterium-metal distance in the M-2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far.

Original language	English
Pages (from-to)	3-8
Number of pages	6
Journal	Chemical Physics
Volume	427
Early online date	28 Aug 2013
DOIs	https://doi.org/10.1016/j.chemphys.2013.08.010
Publication status	Published - 12 Dec 2013

Keywords

Neutron scattering
Hydrogen storage
Metal-organic framework
Porous crystal
Neutron powder diffraction
High H-2 adsorption
Coordination polymer

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10.1016/j.chemphys.2013.08.010

CHEMPHYS-S-13-00381
Copyright 2013, Elsevier. This is the accepted version manuscript of an article published in Chemical Physics. The version of record for this article is available at http://www.sciencedirect.com/science/article/pii/S0301010413003376
Accepted author manuscript, 1.28 MB

Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact
Morris, R. E. (PI)
EPSRC
1/08/13 → 31/07/18
Project: Fellowship
Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks
Morris, R. E. (PI)
EPSRC
1/03/13 → 28/02/16
Project: Standard

Cite this

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title = "Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework",

abstract = "The structure of Ni-2(dobdc) (dobdc(4) = 2,5-dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogs and the Ni2+ variant shows the shortest deuterium-metal distance in the M-2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far.",

keywords = "Neutron scattering, Hydrogen storage, Metal-organic framework, Porous crystal, Neutron powder diffraction, High H-2 adsorption, Coordination polymer",

author = "Brown, {Craig M.} and Ramirez-Cuesta, {Anibal Javier} and Jae-Hyuk Her and Wheatley, {Paul S.} and Morris, {Russell E.}",

year = "2013",

month = dec,

day = "12",

doi = "10.1016/j.chemphys.2013.08.010",

language = "English",

volume = "427",

pages = "3--8",

journal = "Chemical Physics",

issn = "0301-0104",

publisher = "Elsevier Science BV",

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TY - JOUR

T1 - Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework

AU - Brown, Craig M.

AU - Ramirez-Cuesta, Anibal Javier

AU - Her, Jae-Hyuk

AU - Wheatley, Paul S.

AU - Morris, Russell E.

PY - 2013/12/12

Y1 - 2013/12/12

N2 - The structure of Ni-2(dobdc) (dobdc(4) = 2,5-dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogs and the Ni2+ variant shows the shortest deuterium-metal distance in the M-2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far.

AB - The structure of Ni-2(dobdc) (dobdc(4) = 2,5-dioxido-1,4-benzenedicarboxylate) as a function of deuterium adsorption has been determined through the application of in situ neutron powder diffraction. Detailed information concerning the local adsorption potential for hydrogen at each site has also been probed using inelastic neutron scattering techniques. These results are compared to those previously published on isostructural analogs and the Ni2+ variant shows the shortest deuterium-metal distance in the M-2(dobdc) series (M = Mg, Zn, Co, Fe) that have been studied so far.

KW - Neutron scattering

KW - Hydrogen storage

KW - Metal-organic framework

KW - Porous crystal

KW - Neutron powder diffraction

KW - High H-2 adsorption

KW - Coordination polymer

U2 - 10.1016/j.chemphys.2013.08.010

DO - 10.1016/j.chemphys.2013.08.010

M3 - Article

SN - 0301-0104

VL - 427

SP - 3

EP - 8

JO - Chemical Physics

JF - Chemical Physics

ER -

Structure and spectroscopy of hydrogen adsorbed in a nickel metal-organic framework

Abstract

Keywords

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Projects

Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact

Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks

Cite this