Structural parameters for the incomplete cuboidal cluster cation: [Nb3(µ3-Cl)(µ-O)3(OH2)9]4+ in solutions of acid hydrolysed trivalent niobium from Niobium K edge EXAFS

David Trevor Richens; IJ Shannon

doi:10.1039/a804247k

Structural parameters for the incomplete cuboidal cluster cation: [Nb₃(µ₃-Cl)(µ-O)₃(OH₂)₉]⁴+ in solutions of acid hydrolysed trivalent niobium from Niobium K edge EXAFS

David Trevor Richens
, IJ Shannon

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A niobium K edge EXAFS study on the green solutions obtained following hydrolysis of NbCl3(dme) in aqueous non-oxidising strong acids has shown that the major species resulting in these solutions is the incomplete cuboidal chloride-capped triangular niobium cation, [Nb-3(mu(3)-Cl)(mu-O)(3)(OH2)(9)](4+).

Original language	English
Pages (from-to)	2611-2613
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/a804247k
Publication status	Published - 21 Aug 1998

Keywords

TRINUCLEAR
CRYSTAL

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Cite this

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title = "Structural parameters for the incomplete cuboidal cluster cation: [Nb3(µ3-Cl)(µ-O)3(OH2)9]4+ in solutions of acid hydrolysed trivalent niobium from Niobium K edge EXAFS",

abstract = "A niobium K edge EXAFS study on the green solutions obtained following hydrolysis of NbCl3(dme) in aqueous non-oxidising strong acids has shown that the major species resulting in these solutions is the incomplete cuboidal chloride-capped triangular niobium cation, [Nb-3(mu(3)-Cl)(mu-O)(3)(OH2)(9)](4+).",

keywords = "TRINUCLEAR, CRYSTAL",

author = "Richens, \{David Trevor\} and IJ Shannon",

year = "1998",

month = aug,

day = "21",

doi = "10.1039/a804247k",

language = "English",

pages = "2611--2613",

journal = "Journal of the Chemical Society, Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Structural parameters for the incomplete cuboidal cluster cation: [Nb3(µ3-Cl)(µ-O)3(OH2)9]4+ in solutions of acid hydrolysed trivalent niobium from Niobium K edge EXAFS

AU - Richens, David Trevor

AU - Shannon, IJ

PY - 1998/8/21

Y1 - 1998/8/21

N2 - A niobium K edge EXAFS study on the green solutions obtained following hydrolysis of NbCl3(dme) in aqueous non-oxidising strong acids has shown that the major species resulting in these solutions is the incomplete cuboidal chloride-capped triangular niobium cation, [Nb-3(mu(3)-Cl)(mu-O)(3)(OH2)(9)](4+).

AB - A niobium K edge EXAFS study on the green solutions obtained following hydrolysis of NbCl3(dme) in aqueous non-oxidising strong acids has shown that the major species resulting in these solutions is the incomplete cuboidal chloride-capped triangular niobium cation, [Nb-3(mu(3)-Cl)(mu-O)(3)(OH2)(9)](4+).

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KW - CRYSTAL

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U2 - 10.1039/a804247k

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JF - Journal of the Chemical Society, Dalton Transactions

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