Structural parameters for the incomplete cuboidal cluster cation: [Nb33-Cl)(µ-O)3(OH2)9]4+ in solutions of acid hydrolysed trivalent niobium from Niobium K edge EXAFS

David Trevor Richens, IJ Shannon

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8 Citations (Scopus)

Abstract

A niobium K edge EXAFS study on the green solutions obtained following hydrolysis of NbCl3(dme) in aqueous non-oxidising strong acids has shown that the major species resulting in these solutions is the incomplete cuboidal chloride-capped triangular niobium cation, [Nb-3(mu(3)-Cl)(mu-O)(3)(OH2)(9)](4+).

Original languageEnglish
Pages (from-to)2611-2613
Number of pages3
JournalJournal of the Chemical Society, Dalton Transactions
Issue number16
DOIs
Publication statusPublished - 21 Aug 1998

Keywords

  • TRINUCLEAR
  • CRYSTAL

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