Structural characterization and catalytic activity of the rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (IMes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)

G A  Grasa; Z  Moore; K L  Martin; E D  Stevens; Steven Patrick Nolan; V  Paquet; H  Lebel

Structural characterization and catalytic activity of the rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (IMes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)

G A Grasa, Z Moore, K L Martin, E D Stevens, Steven Patrick Nolan, V Paquet, H Lebel

Research output: Contribution to journal › Article › peer-review

Abstract

The rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (2) is an active catalyst for the hydroboration of simple olefins at room temperature. The reactivity of 2 was also tested in the methylenation of aldehydes. The crystal structure of 2 is also reported (C) 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	126-131
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	658
Issue number	1-2
Publication status	Published - 16 Sept 2002

Keywords

structural characterization
catalytic activity
rhodium-carbene complexes
OLEFIN METATHESIS CATALYSTS
HIGHLY SELECTIVE CATALYSTS
N-HETEROCYCLIC CARBENES
HOMOGENEOUS HYDROGENATION
HYDROBORATION REACTIONS
DIOLEFIN COMPLEXES
COUPLING REACTIONS
STABLE CARBENES
ARYL CHLORIDES
IMIDAZOLIN-2-YLIDENE LIGANDS

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title = "Structural characterization and catalytic activity of the rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (IMes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)",

abstract = "The rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (2) is an active catalyst for the hydroboration of simple olefins at room temperature. The reactivity of 2 was also tested in the methylenation of aldehydes. The crystal structure of 2 is also reported (C) 2002 Elsevier Science B.V. All rights reserved.",

keywords = "structural characterization, catalytic activity, rhodium-carbene complexes, OLEFIN METATHESIS CATALYSTS, HIGHLY SELECTIVE CATALYSTS, N-HETEROCYCLIC CARBENES, HOMOGENEOUS HYDROGENATION, HYDROBORATION REACTIONS, DIOLEFIN COMPLEXES, COUPLING REACTIONS, STABLE CARBENES, ARYL CHLORIDES, IMIDAZOLIN-2-YLIDENE LIGANDS",

author = "Grasa, {G A} and Z Moore and Martin, {K L} and Stevens, {E D} and Nolan, {Steven Patrick} and V Paquet and H Lebel",

year = "2002",

month = sep,

day = "16",

language = "English",

volume = "658",

pages = "126--131",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Structural characterization and catalytic activity of the rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (IMes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)

AU - Grasa, G A

AU - Moore, Z

AU - Martin, K L

AU - Stevens, E D

AU - Nolan, Steven Patrick

AU - Paquet, V

AU - Lebel, H

PY - 2002/9/16

Y1 - 2002/9/16

N2 - The rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (2) is an active catalyst for the hydroboration of simple olefins at room temperature. The reactivity of 2 was also tested in the methylenation of aldehydes. The crystal structure of 2 is also reported (C) 2002 Elsevier Science B.V. All rights reserved.

AB - The rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (2) is an active catalyst for the hydroboration of simple olefins at room temperature. The reactivity of 2 was also tested in the methylenation of aldehydes. The crystal structure of 2 is also reported (C) 2002 Elsevier Science B.V. All rights reserved.

KW - structural characterization

KW - catalytic activity

KW - rhodium-carbene complexes

KW - OLEFIN METATHESIS CATALYSTS

KW - HIGHLY SELECTIVE CATALYSTS

KW - N-HETEROCYCLIC CARBENES

KW - HOMOGENEOUS HYDROGENATION

KW - HYDROBORATION REACTIONS

KW - DIOLEFIN COMPLEXES

KW - COUPLING REACTIONS

KW - STABLE CARBENES

KW - ARYL CHLORIDES

KW - IMIDAZOLIN-2-YLIDENE LIGANDS

M3 - Article

SN - 0022-328X

VL - 658

SP - 126

EP - 131

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Structural characterization and catalytic activity of the rhodium-carbene complex Rh(PPh3)(2)(IMes)Cl (IMes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)

Abstract

Keywords

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