Structural characterisation of basic zinc O,O '-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates

S  Menzer; J R  Phillips; A M Z  Slawin; D J  Williams; J D  Woollins

doi:10.1039/b003915m

Structural characterisation of basic zinc O,O '-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates

S Menzer, J R Phillips, A M Z Slawin, D J Williams, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of basic Zn4O[S2P(OBui)(2)](6) revealed a Zn4O core. Two examples of zinc monothiophosphates, Zn-4[O(S)P(OPh)(2)](6)O and Zn-4[O(S)P(OMe)(2)](6)O, have also been synthesized and structurally characterised. These systems also contain a Zn4O core but display an interesting isomerism as a consequence of the unsymmetrical O,S donor ligands.

Original language	English
Pages (from-to)	3269-3273
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	19
DOIs	https://doi.org/10.1039/b003915m
Publication status	Published - 2000

Keywords

HYDROLYSIS
COMPLEXES

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title = "Structural characterisation of basic zinc O,O '-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates",

abstract = "The crystal structure of basic Zn4O[S2P(OBui)(2)](6) revealed a Zn4O core. Two examples of zinc monothiophosphates, Zn-4[O(S)P(OPh)(2)](6)O and Zn-4[O(S)P(OMe)(2)](6)O, have also been synthesized and structurally characterised. These systems also contain a Zn4O core but display an interesting isomerism as a consequence of the unsymmetrical O,S donor ligands.",

keywords = "HYDROLYSIS, COMPLEXES",

author = "S Menzer and Phillips, {J R} and Slawin, {A M Z} and Williams, {D J} and Woollins, {J D}",

year = "2000",

doi = "10.1039/b003915m",

language = "English",

pages = "3269--3273",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "19",

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T1 - Structural characterisation of basic zinc O,O '-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates

AU - Menzer, S

AU - Phillips, J R

AU - Slawin, A M Z

AU - Williams, D J

AU - Woollins, J D

PY - 2000

Y1 - 2000

N2 - The crystal structure of basic Zn4O[S2P(OBui)(2)](6) revealed a Zn4O core. Two examples of zinc monothiophosphates, Zn-4[O(S)P(OPh)(2)](6)O and Zn-4[O(S)P(OMe)(2)](6)O, have also been synthesized and structurally characterised. These systems also contain a Zn4O core but display an interesting isomerism as a consequence of the unsymmetrical O,S donor ligands.

AB - The crystal structure of basic Zn4O[S2P(OBui)(2)](6) revealed a Zn4O core. Two examples of zinc monothiophosphates, Zn-4[O(S)P(OPh)(2)](6)O and Zn-4[O(S)P(OMe)(2)](6)O, have also been synthesized and structurally characterised. These systems also contain a Zn4O core but display an interesting isomerism as a consequence of the unsymmetrical O,S donor ligands.

KW - HYDROLYSIS

KW - COMPLEXES

U2 - 10.1039/b003915m

DO - 10.1039/b003915m

M3 - Article

SN - 1470-479X

SP - 3269

EP - 3273

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 19

ER -

Structural characterisation of basic zinc O,O '-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates

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