Strongly hydrogen bonded interlocked infinite double helices in a crown ether based gadolinium(III) hexacyanoferrate(III) supramolecule

R  Koner; M  Nayak; G  Ferguson; J N  Low; C  Glidewell; P  Misra; S  Mohanta

doi:10.1039/b418173e

Strongly hydrogen bonded interlocked infinite double helices in a crown ether based gadolinium(III) hexacyanoferrate(III) supramolecule

R Koner, M Nayak, G Ferguson, J N Low, C Glidewell, P Misra, S Mohanta

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The strong O - H ... N and O - H ... O hydrogen bonds involving two types of crystallographically different hexacyanoferrate( III) anions and water molecules in[Gd-III(18- crown- 6)( H2O)(3)][ Fe-III(CN)(6)] . 2H(2)O result in 3-D assembly consisting of the novel example of interlocked infinite double helices.

Original language	English
Pages (from-to)	129-132
Number of pages	4
Journal	CrystEngComm
Volume	7
DOIs	https://doi.org/10.1039/b418173e
Publication status	Published - 28 Jan 2005

Keywords

COMPLEXES
RECOGNITION
TWIST

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10.1039/b418173e

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abstract = "The strong O - H ... N and O - H ... O hydrogen bonds involving two types of crystallographically different hexacyanoferrate( III) anions and water molecules in[Gd-III(18- crown- 6)( H2O)(3)][ Fe-III(CN)(6)] . 2H(2)O result in 3-D assembly consisting of the novel example of interlocked infinite double helices.",

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author = "R Koner and M Nayak and G Ferguson and Low, {J N} and C Glidewell and P Misra and S Mohanta",

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doi = "10.1039/b418173e",

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AU - Koner, R

AU - Nayak, M

AU - Ferguson, G

AU - Low, J N

AU - Glidewell, C

AU - Misra, P

AU - Mohanta, S

PY - 2005/1/28

Y1 - 2005/1/28

N2 - The strong O - H ... N and O - H ... O hydrogen bonds involving two types of crystallographically different hexacyanoferrate( III) anions and water molecules in[Gd-III(18- crown- 6)( H2O)(3)][ Fe-III(CN)(6)] . 2H(2)O result in 3-D assembly consisting of the novel example of interlocked infinite double helices.

AB - The strong O - H ... N and O - H ... O hydrogen bonds involving two types of crystallographically different hexacyanoferrate( III) anions and water molecules in[Gd-III(18- crown- 6)( H2O)(3)][ Fe-III(CN)(6)] . 2H(2)O result in 3-D assembly consisting of the novel example of interlocked infinite double helices.

KW - COMPLEXES

KW - RECOGNITION

KW - TWIST

U2 - 10.1039/b418173e

DO - 10.1039/b418173e

M3 - Article

SN - 1466-8033

VL - 7

SP - 129

EP - 132

JO - CrystEngComm

JF - CrystEngComm

ER -

Strongly hydrogen bonded interlocked infinite double helices in a crown ether based gadolinium(III) hexacyanoferrate(III) supramolecule

Abstract

Keywords

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