Strong magnetic exchange and frustrated ferrimagnetic order in a weberite-type inorganic-organic hybrid fluoride

L Clark, V Pimenta, J Lhoste, I da Silva, C Payen, J.-M. Grenèche, V Maisonneuve, Philip Lightfoot, M Leblanc

Research output: Contribution to journalArticlepeer-review

Abstract

We combine powder neutron diffraction, magnetometry and 57Fe Mössbauer spectrometry to determine the nuclear and magnetic structures of a strongly interacting weberite-type inorganic-organic hybrid fluoride, Fe2F5(Htaz). In this structure, Fe2+ and Fe3+ cations form magnetically frustrated hexagonal tungsten bronze (HTB) layers of corner sharing octahedra. Our powder neutron diffraction data reveal that, unlike its purely inorganic fluoride weberite counterparts which adopt a centrosymmetric Imma structure, the room- temperature nuclear structure of Fe2F5(Htaz) is best described by a non centrosymmetric Ima2 model with refined lattice parameters a = 9.1467(2) Å, b = 9.4641(2) Å and c = 7.4829(2) Å. Magnetic susceptibility and magnetisation measurements reveal that strong antiferromagnetic exchange interactions prevail in Fe2F5(Htaz) leading to a magnetic ordering transition at TN = 93 K. Analysis of low-temperature powder neutron diffraction data indicates that below TN, the Fe2+ sublattice is ferromagnetic, with a moment of 4.1(1) μB per Fe2+ at 2 K, but that an antiferromagnetic component of 0.6(3) μB cants the main ferromagnetic component of Fe3+, which aligns antiferromagnetically to the Fe2+ sublattice. The zero-field and in-field Mössbauer spectra give clear evidence of an excess of high-spin Fe3+ species within the structure and a non collinear magnetic structure.
Original languageEnglish
JournalPhilosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences
Volume377
Issue number2149
Early online date27 May 2019
DOIs
Publication statusPublished - Jul 2019

Keywords

  • Neutron diffraction
  • Fluorides
  • 57Fe Mössbauer spectrometry
  • Coordination frameworks

Fingerprint

Dive into the research topics of 'Strong magnetic exchange and frustrated ferrimagnetic order in a weberite-type inorganic-organic hybrid fluoride'. Together they form a unique fingerprint.

Cite this