TY - JOUR
T1 - Steric effects in triorganosilanes
T2 - Crystal and molecular structure of tribenzylsilane, a silane isomorphous with the corresponding silanol
AU - Glidewell, Christopher
AU - Lightfoot, Philip
PY - 1994/12/27
Y1 - 1994/12/27
N2 - The structure of tribenzylsilane, (PhCH2)3SiH, has been determined from single-crystal X-ray diffraction data. The crystal consists of isolated molecules with approximate three-fold rotational symmetry. The compound is isomorphous, and effectively isostructural, with tribenzylsilanol (PhCH2)3SiOH; the crystal structures are discussed in terms of the preferred molecular conformations.
AB - The structure of tribenzylsilane, (PhCH2)3SiH, has been determined from single-crystal X-ray diffraction data. The crystal consists of isolated molecules with approximate three-fold rotational symmetry. The compound is isomorphous, and effectively isostructural, with tribenzylsilanol (PhCH2)3SiOH; the crystal structures are discussed in terms of the preferred molecular conformations.
KW - Crystal Structure
KW - Silanol
KW - Silicon
UR - http://www.scopus.com/inward/record.url?scp=0011568813&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(94)87202-3
DO - 10.1016/0022-328X(94)87202-3
M3 - Article
AN - SCOPUS:0011568813
SN - 0022-328X
VL - 484
SP - 175
EP - 178
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1-2
ER -