Steric and Electronic Parameters of a Bulky yet Flexible N-Heterocyclic Carbene: 1,3-Bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)

Alba Collado-Martinez; Janos Balogh; Sebastien Michel Bernard Meiries; Alexandra Martha Zoya Slawin; Laura Falivene; Luigi Cavallo; Steven Patrick Nolan

doi:10.1021/om400168b

Steric and Electronic Parameters of a Bulky yet Flexible N-Heterocyclic Carbene: 1,3-Bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)

Alba Collado-Martinez
, Janos Balogh
, Sebastien Michel Bernard Meiries
, Alexandra Martha Zoya Slawin
, Laura Falivene
, Luigi Cavallo
, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The free N-heterocyclic carbene IPent (1;IPent = 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene) was prepared from the corresponding imidazolium chloride salt (2). The steric and electronic parameters of 1
were determined by synthesis of the gold(I) chloride complex [Au(IPent)Cl] (3) and the nickel−carbonyl complex [Ni-(IPent)(CO)3] (4), respectively. 3 and 4 were fully
characterized by NMR spectroscopy, elemental analysis, and X-ray diffraction studies on single crystals.

Original language	English
Pages (from-to)	3249-3252
Number of pages	4
Journal	Organometallics
Volume	32
Issue number	11
Early online date	28 May 2013
DOIs	https://doi.org/10.1021/om400168b
Publication status	Published - 10 Jun 2013

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title = "Steric and Electronic Parameters of a Bulky yet Flexible N-Heterocyclic Carbene: 1,3-Bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)",

abstract = "The free N-heterocyclic carbene IPent (1;IPent = 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene) was prepared from the corresponding imidazolium chloride salt (2). The steric and electronic parameters of 1 were determined by synthesis of the gold(I) chloride complex [Au(IPent)Cl] (3) and the nickel−carbonyl complex [Ni-(IPent)(CO)3] (4), respectively. 3 and 4 were fully characterized by NMR spectroscopy, elemental analysis, and X-ray diffraction studies on single crystals.",

author = "Alba Collado-Martinez and Janos Balogh and Meiries, \{Sebastien Michel Bernard\} and Slawin, \{Alexandra Martha Zoya\} and Laura Falivene and Luigi Cavallo and Nolan, \{Steven Patrick\}",

year = "2013",

month = jun,

day = "10",

doi = "10.1021/om400168b",

language = "English",

volume = "32",

pages = "3249--3252",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society (ACS)",

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TY - JOUR

T1 - Steric and Electronic Parameters of a Bulky yet Flexible N-Heterocyclic Carbene

T2 - 1,3-Bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)

AU - Collado-Martinez, Alba

AU - Balogh, Janos

AU - Meiries, Sebastien Michel Bernard

AU - Slawin, Alexandra Martha Zoya

AU - Falivene, Laura

AU - Cavallo, Luigi

AU - Nolan, Steven Patrick

PY - 2013/6/10

Y1 - 2013/6/10

N2 - The free N-heterocyclic carbene IPent (1;IPent = 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene) was prepared from the corresponding imidazolium chloride salt (2). The steric and electronic parameters of 1 were determined by synthesis of the gold(I) chloride complex [Au(IPent)Cl] (3) and the nickel−carbonyl complex [Ni-(IPent)(CO)3] (4), respectively. 3 and 4 were fully characterized by NMR spectroscopy, elemental analysis, and X-ray diffraction studies on single crystals.

AB - The free N-heterocyclic carbene IPent (1;IPent = 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene) was prepared from the corresponding imidazolium chloride salt (2). The steric and electronic parameters of 1 were determined by synthesis of the gold(I) chloride complex [Au(IPent)Cl] (3) and the nickel−carbonyl complex [Ni-(IPent)(CO)3] (4), respectively. 3 and 4 were fully characterized by NMR spectroscopy, elemental analysis, and X-ray diffraction studies on single crystals.

U2 - 10.1021/om400168b

DO - 10.1021/om400168b

M3 - Article

SN - 0276-7333

VL - 32

SP - 3249

EP - 3252

JO - Organometallics

JF - Organometallics

IS - 11

ER -

Steric and Electronic Parameters of a Bulky yet Flexible N-Heterocyclic Carbene: 1,3-Bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)

Abstract

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