Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

A E C  McConnell; D F  Foster; P  Pogorzelec; A M Z  Slawin; D J  Law; D J  Cole-Hamilton

doi:10.1039/b211287f

Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

A E C McConnell
, D F Foster
, P Pogorzelec
, A M Z Slawin
, D J Law
, D J Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

(Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

Original language	English
Pages (from-to)	510-512
Number of pages	3
Journal	Dalton Transactions
Issue number	4
DOIs	https://doi.org/10.1039/b211287f
Publication status	Published - 2003

Keywords

MOLECULAR-STRUCTURE
COMPLEXES
CRYSTAL
CARBONYLATION
METHANOL
RHODIUM

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title = "Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands",

abstract = "(Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.",

keywords = "MOLECULAR-STRUCTURE, COMPLEXES, CRYSTAL, CARBONYLATION, METHANOL, RHODIUM",

author = "McConnell, \{A E C\} and Foster, \{D F\} and P Pogorzelec and Slawin, \{A M Z\} and Law, \{D J\} and Cole-Hamilton, \{D J\}",

year = "2003",

doi = "10.1039/b211287f",

language = "English",

pages = "510--512",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "4",

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TY - JOUR

T1 - Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

AU - McConnell, A E C

AU - Foster, D F

AU - Pogorzelec, P

AU - Slawin, A M Z

AU - Law, D J

AU - Cole-Hamilton, D J

PY - 2003

Y1 - 2003

N2 - (Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

AB - (Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

KW - MOLECULAR-STRUCTURE

KW - COMPLEXES

KW - CRYSTAL

KW - CARBONYLATION

KW - METHANOL

KW - RHODIUM

UR - https://www.scopus.com/pages/publications/0037458346

U2 - 10.1039/b211287f

DO - 10.1039/b211287f

M3 - Article

SN - 1477-9226

SP - 510

EP - 512

JO - Dalton Transactions

JF - Dalton Transactions

IS - 4

ER -

Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

Abstract

Keywords

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