Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

A E C  McConnell; D F  Foster; P  Pogorzelec; A M Z  Slawin; D J  Law; D J  Cole-Hamilton

doi:10.1039/b211287f

Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

A E C McConnell, D F Foster, P Pogorzelec, A M Z Slawin, D J Law, D J Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

(Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

Original language	English
Pages (from-to)	510-512
Number of pages	3
Journal	Dalton Transactions
Issue number	4
DOIs	https://doi.org/10.1039/b211287f
Publication status	Published - 2003

Keywords

MOLECULAR-STRUCTURE
COMPLEXES
CRYSTAL
CARBONYLATION
METHANOL
RHODIUM

Access to Document

10.1039/b211287f

Cite this

@article{df82bde1fdf946669ff62c6cbc8db36c,

title = "Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands",

abstract = "(Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.",

keywords = "MOLECULAR-STRUCTURE, COMPLEXES, CRYSTAL, CARBONYLATION, METHANOL, RHODIUM",

author = "McConnell, {A E C} and Foster, {D F} and P Pogorzelec and Slawin, {A M Z} and Law, {D J} and Cole-Hamilton, {D J}",

year = "2003",

doi = "10.1039/b211287f",

language = "English",

pages = "510--512",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "4",

}

TY - JOUR

T1 - Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

AU - McConnell, A E C

AU - Foster, D F

AU - Pogorzelec, P

AU - Slawin, A M Z

AU - Law, D J

AU - Cole-Hamilton, D J

PY - 2003

Y1 - 2003

N2 - (Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

AB - (Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

KW - MOLECULAR-STRUCTURE

KW - COMPLEXES

KW - CRYSTAL

KW - CARBONYLATION

KW - METHANOL

KW - RHODIUM

UR - http://www.scopus.com/inward/record.url?scp=0037458346&partnerID=8YFLogxK

U2 - 10.1039/b211287f

DO - 10.1039/b211287f

M3 - Article

SN - 1477-9226

SP - 510

EP - 512

JO - Dalton Transactions

JF - Dalton Transactions

IS - 4

ER -

Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this