Stabilising Rh-P coordination by phosphanylalkylcyclopentadienyl ligands

A E C McConnell, D F Foster, P Pogorzelec, A M Z Slawin, D J Law, D J Cole-Hamilton

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

(Phosphanylalkyl/aryl) cyclopentadienyl complexes have been synthesised from lithiated 1,2,3,4-tetramethyl-5-(2-P,P-dialkyl/arylphosphinoethyl) cyclopentadiene and [RhCl(CO)(2)](2); the electron donating properties of these ligands have been compared and the P-Rh interaction is shown to be stable under methanol carbonylation reaction conditions.

Original languageEnglish
Pages (from-to)510-512
Number of pages3
JournalDalton Transactions
Issue number4
DOIs
Publication statusPublished - 2003

Keywords

  • MOLECULAR-STRUCTURE
  • COMPLEXES
  • CRYSTAL
  • CARBONYLATION
  • METHANOL
  • RHODIUM

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