TY - JOUR
T1 - Spectroelectrochemistry of copper(II) complexes with deprotonated tetradentate pyridine-2-carboxamide ligands: EC reaction of the electrogenerated Cu(III) species
AU - Jain, SL
AU - Crayston, Joseph Alan
AU - Richens, David Trevor
AU - Woollins, John Derek
PY - 2002/10
Y1 - 2002/10
N2 - The electrochemistry of [CuL1] I and [CuL2] 2 [H2L1 = 1,2-bis(pyridine-2-carboxdmido)benzene, H2L2 = 3,4-bis(pyridine-2-carboxamido)toluene] was investigated. Both complexes show a quasi-reversible Cu(II/I) reduction near -1.6 V vs Fc(+)/Fc. Spectroelectrochemistry confirmed that the Cu(III) state is accessible near +0.4 V, and undergoes an EC reaction (k similar or equal to 10 s(-1)) to generate a new Cu(II) species. (C) 2002 Elsevier Science B.V. All rights reserved.
AB - The electrochemistry of [CuL1] I and [CuL2] 2 [H2L1 = 1,2-bis(pyridine-2-carboxdmido)benzene, H2L2 = 3,4-bis(pyridine-2-carboxamido)toluene] was investigated. Both complexes show a quasi-reversible Cu(II/I) reduction near -1.6 V vs Fc(+)/Fc. Spectroelectrochemistry confirmed that the Cu(III) state is accessible near +0.4 V, and undergoes an EC reaction (k similar or equal to 10 s(-1)) to generate a new Cu(II) species. (C) 2002 Elsevier Science B.V. All rights reserved.
KW - copper(II)/(III)/(I)
KW - tetradentate ligands
KW - mononuclear
KW - electrochemistry
KW - EC reaction
KW - NICKEL(III)
UR - http://www.scopus.com/inward/record.url?scp=0036826283&partnerID=8YFLogxK
UR - http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6VM7-46RVHDY-3-1X&_cdi=6143&_user=1026342&_orig=search&_coverDate=10%2F31%2F2002&_sk=999949989&view=c&wchp=dGLzVlz-zSkzS&md5=b35de47c798b49606766c8a28e4dd163&ie=/sdarticle.pdf
U2 - 10.1016/S1387-7003(02)00589-0
DO - 10.1016/S1387-7003(02)00589-0
M3 - Article
SN - 1387-7003
VL - 5
SP - 853
EP - 855
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -