Specific autocatalysis in diastereoisomeric replicators

E Kassianidis; R J Pearson; Douglas Philp

doi:10.1021/ol051179r

Specific autocatalysis in diastereoisomeric replicators

E Kassianidis, R J Pearson, Douglas Philp

Research output: Contribution to journal › Article › peer-review

Abstract

Two diastereoisomeric cycloadducts are capable of accelerating their own formation through the assembly of catalytic ternary complexes. The two cycloadducts do not have any measurable catalytic effect on the rate of formation of their diastereoisomer.

Original language	English
Pages (from-to)	3833-3836
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	18
DOIs	https://doi.org/10.1021/ol051179r
Publication status	Published - 1 Sept 2005

Keywords

DIELS-ALDER REACTION
SELF-REPLICATION
MACHINES
SYSTEMS

Access to Document

10.1021/ol051179r

Cite this

@article{a437cbb4976b491b9f07f7638a922b6e,

title = "Specific autocatalysis in diastereoisomeric replicators",

abstract = "Two diastereoisomeric cycloadducts are capable of accelerating their own formation through the assembly of catalytic ternary complexes. The two cycloadducts do not have any measurable catalytic effect on the rate of formation of their diastereoisomer.",

keywords = "DIELS-ALDER REACTION, SELF-REPLICATION, MACHINES, SYSTEMS",

author = "E Kassianidis and Pearson, {R J} and Douglas Philp",

year = "2005",

month = sep,

day = "1",

doi = "10.1021/ol051179r",

language = "English",

volume = "7",

pages = "3833--3836",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society (ACS)",

number = "18",

}

TY - JOUR

T1 - Specific autocatalysis in diastereoisomeric replicators

AU - Kassianidis, E

AU - Pearson, R J

AU - Philp, Douglas

PY - 2005/9/1

Y1 - 2005/9/1

N2 - Two diastereoisomeric cycloadducts are capable of accelerating their own formation through the assembly of catalytic ternary complexes. The two cycloadducts do not have any measurable catalytic effect on the rate of formation of their diastereoisomer.

AB - Two diastereoisomeric cycloadducts are capable of accelerating their own formation through the assembly of catalytic ternary complexes. The two cycloadducts do not have any measurable catalytic effect on the rate of formation of their diastereoisomer.

KW - DIELS-ALDER REACTION

KW - SELF-REPLICATION

KW - MACHINES

KW - SYSTEMS

UR - http://www.scopus.com/inward/record.url?scp=24944498176&partnerID=8YFLogxK

U2 - 10.1021/ol051179r

DO - 10.1021/ol051179r

M3 - Article

SN - 1523-7060

VL - 7

SP - 3833

EP - 3836

JO - Organic Letters

JF - Organic Letters

IS - 18

ER -

Specific autocatalysis in diastereoisomeric replicators

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

BBSRC B20102: Probing the relative efficiencies of direct and reciprocal replication strategies

Cite this

Specific autocatalysis in diastereoisomeric replicators

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Projects

BBSRC B20102: Probing the relative efficiencies of direct and reciprocal replication strategies

Cite this