Some Schiff base complexes of lead(II)

J  Parr; A T  Ross; A M Z  Slawin

Some Schiff base complexes of lead(II)

J Parr, A T Ross, A M Z Slawin

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Abstract

The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.

Original language	English
Pages (from-to)	1509-1512
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	8
Publication status	Published - 21 Apr 1996

Keywords

SEQUESTERING AGENTS
LIGANDS

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title = "Some Schiff base complexes of lead(II)",

abstract = "The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.",

keywords = "SEQUESTERING AGENTS, LIGANDS",

author = "J Parr and Ross, \{A T\} and Slawin, \{A M Z\}",

year = "1996",

month = apr,

day = "21",

language = "English",

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journal = "Journal of the Chemical Society, Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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T1 - Some Schiff base complexes of lead(II)

AU - Parr, J

AU - Ross, A T

AU - Slawin, A M Z

PY - 1996/4/21

Y1 - 1996/4/21

N2 - The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.

AB - The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.

KW - SEQUESTERING AGENTS

KW - LIGANDS

UR - https://www.scopus.com/pages/publications/33751374258

M3 - Article

SN - 0300-9246

SP - 1509

EP - 1512

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 8

ER -

Some Schiff base complexes of lead(II)

Abstract

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