Some Schiff base complexes of lead(II)

J  Parr; A T  Ross; A M Z  Slawin

Some Schiff base complexes of lead(II)

J Parr, A T Ross, A M Z Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.

Original language	English
Pages (from-to)	1509-1512
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	8
Publication status	Published - 21 Apr 1996

Keywords

SEQUESTERING AGENTS
LIGANDS

Cite this

@article{fc137a84680045d0b2b421c6cabdec2e,

title = "Some Schiff base complexes of lead(II)",

abstract = "The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.",

keywords = "SEQUESTERING AGENTS, LIGANDS",

author = "J Parr and Ross, {A T} and Slawin, {A M Z}",

year = "1996",

month = apr,

day = "21",

language = "English",

pages = "1509--1512",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "8",

}

TY - JOUR

T1 - Some Schiff base complexes of lead(II)

AU - Parr, J

AU - Ross, A T

AU - Slawin, A M Z

PY - 1996/4/21

Y1 - 1996/4/21

N2 - The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.

AB - The interaction of lead(II) salts with the Schiff bases N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) and tris[2-(N-salicylideneamino)ethyl]amine (H(3)saltren) resulted in formation of the new complexes [(Pb-3(salen)(2)][ClO4](2) 1 and [Pb(saltren)] 2. The crystal structures of both complexes have been determined: 1 is a hitherto unreported trimetallic lead species in which the ligand bonds to lead in two different modes; in 2 some sites on the ligand are not involved in bonding to the metal.

KW - SEQUESTERING AGENTS

KW - LIGANDS

M3 - Article

SN - 0300-9246

SP - 1509

EP - 1512

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 8

ER -

Some Schiff base complexes of lead(II)

Abstract

Keywords

Fingerprint

Cite this