Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

David S. Wragg; Grace M. Fullerton; Peter J. Byrne; Alexandra M. Z. Slawin; John E. Warren; Simon J. Teat; Russell E. Morris

doi:10.1039/c0dt01788d

Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

David S. Wragg, Grace M. Fullerton, Peter J. Byrne, Alexandra M. Z. Slawin, John E. Warren, Simon J. Teat, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented.

Original language	English
Pages (from-to)	4926-4932
Number of pages	7
Journal	Dalton Transactions
Volume	40
Issue number	18
Early online date	24 Mar 2011
DOIs	https://doi.org/10.1039/c0dt01788d
Publication status	Published - 14 May 2011

Keywords

METAL-ORGANIC FRAMEWORKS
DEEP-EUTECTIC SOLVENTS
IONOTHERMAL SYNTHESIS
GALLIUM PHOSPHATE
MOLECULAR-SIEVES
RAPID THERMOLYSIS/FTIR/TOF
LAYERED ALUMINOPHOSPHATE
CHAIN ALUMINOPHOSPHATE
COORDINATION POLYMERS
POROUS MATERIALS

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10.1039/c0dt01788d

EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues
Morris, R. E. (PI)
EPSRC
1/07/05 → 31/12/08
Project: Standard

Cite this

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title = "Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors",

abstract = "We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented.",

keywords = "METAL-ORGANIC FRAMEWORKS, DEEP-EUTECTIC SOLVENTS, IONOTHERMAL SYNTHESIS, GALLIUM PHOSPHATE, MOLECULAR-SIEVES, RAPID THERMOLYSIS/FTIR/TOF, LAYERED ALUMINOPHOSPHATE, CHAIN ALUMINOPHOSPHATE, COORDINATION POLYMERS, POROUS MATERIALS",

author = "Wragg, {David S.} and Fullerton, {Grace M.} and Byrne, {Peter J.} and Slawin, {Alexandra M. Z.} and Warren, {John E.} and Teat, {Simon J.} and Morris, {Russell E.}",

year = "2011",

month = may,

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doi = "10.1039/c0dt01788d",

language = "English",

volume = "40",

pages = "4926--4932",

journal = "Dalton Transactions",

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T1 - Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

AU - Wragg, David S.

AU - Fullerton, Grace M.

AU - Byrne, Peter J.

AU - Slawin, Alexandra M. Z.

AU - Warren, John E.

AU - Teat, Simon J.

AU - Morris, Russell E.

PY - 2011/5/14

Y1 - 2011/5/14

N2 - We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented.

AB - We have carried out a study of aluminophosphate framework synthesis using several amine based ionic liquids and their parent amines as solvent and template. The results suggest that in the presence of fluoride ions from hydrofluoric acid the ionic liquids and their parent amines produce the same frameworks, while in synthesis without fluoride ions the products are not related. The results include the synthesis and crystal structure of a novel extra-large pore material using 1-methylpyrrolidine as solvent and template. The relationship between this and sodalite, which can be synthesised in cobalt aluminophosphate form using an ionic liquid prepared from 1-methylpyrrolidine is described. The crystal structures of two other new layered materials are also presented.

KW - METAL-ORGANIC FRAMEWORKS

KW - DEEP-EUTECTIC SOLVENTS

KW - IONOTHERMAL SYNTHESIS

KW - GALLIUM PHOSPHATE

KW - MOLECULAR-SIEVES

KW - RAPID THERMOLYSIS/FTIR/TOF

KW - LAYERED ALUMINOPHOSPHATE

KW - CHAIN ALUMINOPHOSPHATE

KW - COORDINATION POLYMERS

KW - POROUS MATERIALS

U2 - 10.1039/c0dt01788d

DO - 10.1039/c0dt01788d

M3 - Article

SN - 1477-9226

VL - 40

SP - 4926

EP - 4932

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Solvothermal aluminophosphate zeotype synthesis with ionic liquid precursors

Abstract

Keywords

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Projects

EP/C006526/1: The ionothermal synthesis of zeolites and zeolites analogues

Cite this