Solvent-free aryl amination catalysed by [Pd)NHC)] complexes

Anthony Raymond Georges Chartoire; Arnaud Boreux; Anthony Martin; Steven Patrick Nolan

doi:10.1039/c3ra40386f

Solvent-free aryl amination catalysed by [Pd)NHC)] complexes

Anthony Raymond Georges Chartoire, Arnaud Boreux, Anthony Martin, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

A highly effective solvent-free protocol for the Buchwald-Hartwig amination of unactivated aryl chlorides is described. The effect of various [Pd)NHC)] pre-catalyst systems on the reactivity has been studied. [pd(IPr*)(cin)Cl] is reported as the complex of choice for the transformation.

Original language	English
Pages (from-to)	3840-3843
Number of pages	4
Journal	RSC Advances
Volume	3
Early online date	13 Feb 2013
DOIs	https://doi.org/10.1039/c3ra40386f
Publication status	Published - 2013

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title = "Solvent-free aryl amination catalysed by [Pd)NHC)] complexes",

abstract = "A highly effective solvent-free protocol for the Buchwald-Hartwig amination of unactivated aryl chlorides is described. The effect of various [Pd)NHC)] pre-catalyst systems on the reactivity has been studied. [pd(IPr*)(cin)Cl] is reported as the complex of choice for the transformation.",

author = "Chartoire, {Anthony Raymond Georges} and Arnaud Boreux and Anthony Martin and Nolan, {Steven Patrick}",

year = "2013",

doi = "10.1039/c3ra40386f",

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T1 - Solvent-free aryl amination catalysed by [Pd)NHC)] complexes

AU - Chartoire, Anthony Raymond Georges

AU - Boreux, Arnaud

AU - Martin, Anthony

AU - Nolan, Steven Patrick

PY - 2013

Y1 - 2013

N2 - A highly effective solvent-free protocol for the Buchwald-Hartwig amination of unactivated aryl chlorides is described. The effect of various [Pd)NHC)] pre-catalyst systems on the reactivity has been studied. [pd(IPr*)(cin)Cl] is reported as the complex of choice for the transformation.

AB - A highly effective solvent-free protocol for the Buchwald-Hartwig amination of unactivated aryl chlorides is described. The effect of various [Pd)NHC)] pre-catalyst systems on the reactivity has been studied. [pd(IPr*)(cin)Cl] is reported as the complex of choice for the transformation.

U2 - 10.1039/c3ra40386f

DO - 10.1039/c3ra40386f

M3 - Article

SN - 2046-2069

VL - 3

SP - 3840

EP - 3843

JO - RSC Advances

JF - RSC Advances

ER -

Solvent-free aryl amination catalysed by [Pd)NHC)] complexes

Abstract

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