Solid-state electrolytes for lithium-ion batteries

Sanoop Palakkathodi Kammampata; Mohammad Akbari Garakani; Zheyu Zhang; Venkataraman Thangadurai

doi:10.1016/B978-0-12-823144-9.00131-X

Solid-state electrolytes for lithium-ion batteries

Sanoop Palakkathodi Kammampata, Mohammad Akbari Garakani, Zheyu Zhang, Venkataraman Thangadurai^*

^*Corresponding author for this work

School of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

This chapter aims to provide a systematic overview of the current state of the research in the field of solid-state electrolytes for all-solid-state Li batteries. The desired functional properties and ion transport mechanism of solid-state electrolytes are explained, followed by a detailed survey on the existing understanding of the metal oxides, sulfides, and halides for fast Li ion conduction. Emphasis is also given on the oxide-based Li ion solid electrolyte, covering the structures of perovskites, Na super ionic conductors (NASICONs)-type, Li super ionic conductors (LISICONs) and Li-stuffed garnets with their chemical composition-crystal structure-ionic conductivity relationships and electrochemical stability discussed. Examples of all-solid-state Li batteries and the evaluation of their performance in terms of capacity and cycle numbers are reported.

Original language	English
Title of host publication	Comprehensive inorganic chemistry III
Editors	Jan Reedijk, Kenneth R. Poeppelmeier, Risto S. Laitinen
Place of Publication	Amsterdam
Publisher	Elsevier Inc.
Chapter	4.19
Pages	658-680
Number of pages	23
Edition	3rd
ISBN (Electronic)	9780128231531
ISBN (Print)	9780128231449
DOIs	https://doi.org/10.1016/B978-0-12-823144-9.00131-X
Publication status	Published - 16 Mar 2023

Keywords

All-solid-state Li battery
Crystal structure
Ionic conductivity
Solid Li ion electrolytes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/B978-0-12-823144-9.00131-X

Cite this

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title = "Solid-state electrolytes for lithium-ion batteries",

abstract = "This chapter aims to provide a systematic overview of the current state of the research in the field of solid-state electrolytes for all-solid-state Li batteries. The desired functional properties and ion transport mechanism of solid-state electrolytes are explained, followed by a detailed survey on the existing understanding of the metal oxides, sulfides, and halides for fast Li ion conduction. Emphasis is also given on the oxide-based Li ion solid electrolyte, covering the structures of perovskites, Na super ionic conductors (NASICONs)-type, Li super ionic conductors (LISICONs) and Li-stuffed garnets with their chemical composition-crystal structure-ionic conductivity relationships and electrochemical stability discussed. Examples of all-solid-state Li batteries and the evaluation of their performance in terms of capacity and cycle numbers are reported.",

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AU - Garakani, Mohammad Akbari

AU - Zhang, Zheyu

AU - Thangadurai, Venkataraman

PY - 2023/3/16

Y1 - 2023/3/16

N2 - This chapter aims to provide a systematic overview of the current state of the research in the field of solid-state electrolytes for all-solid-state Li batteries. The desired functional properties and ion transport mechanism of solid-state electrolytes are explained, followed by a detailed survey on the existing understanding of the metal oxides, sulfides, and halides for fast Li ion conduction. Emphasis is also given on the oxide-based Li ion solid electrolyte, covering the structures of perovskites, Na super ionic conductors (NASICONs)-type, Li super ionic conductors (LISICONs) and Li-stuffed garnets with their chemical composition-crystal structure-ionic conductivity relationships and electrochemical stability discussed. Examples of all-solid-state Li batteries and the evaluation of their performance in terms of capacity and cycle numbers are reported.

AB - This chapter aims to provide a systematic overview of the current state of the research in the field of solid-state electrolytes for all-solid-state Li batteries. The desired functional properties and ion transport mechanism of solid-state electrolytes are explained, followed by a detailed survey on the existing understanding of the metal oxides, sulfides, and halides for fast Li ion conduction. Emphasis is also given on the oxide-based Li ion solid electrolyte, covering the structures of perovskites, Na super ionic conductors (NASICONs)-type, Li super ionic conductors (LISICONs) and Li-stuffed garnets with their chemical composition-crystal structure-ionic conductivity relationships and electrochemical stability discussed. Examples of all-solid-state Li batteries and the evaluation of their performance in terms of capacity and cycle numbers are reported.

KW - All-solid-state Li battery

KW - Crystal structure

KW - Ionic conductivity

KW - Solid Li ion electrolytes

UR - https://doi.org/10.1016/c2019-0-02498-3

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BT - Comprehensive inorganic chemistry III

A2 - Reedijk, Jan

A2 - Poeppelmeier, Kenneth R.

A2 - Laitinen, Risto S.

PB - Elsevier Inc.

CY - Amsterdam

ER -

Solid-state electrolytes for lithium-ion batteries

Abstract

Keywords

UN SDGs

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