Solid-State Confinement Effects in Selective exo-H/D Exchange in the Rhodium σ-Norbornane Complex [(Cy2PCH2CH2PCy2)Rh(η2:η2-C7H12)][BArF4]

T Krämer; FM Chadwick; SA Macgregor; AS Weller

doi:10.1002/hlca.202200154

Solid-State Confinement Effects in Selective exo-H/D Exchange in the Rhodium σ-Norbornane Complex [(Cy₂PCH₂CH₂PCy₂)Rh(η²:η²-C₇H₁₂)][BAr^F₄]

T Krämer, FM Chadwick, SA Macgregor, AS Weller

School of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Original language	English
Number of pages	13
Journal	Helvetica Chimica Acta
Volume	106
Issue number	2
DOIs	https://doi.org/10.1002/hlca.202200154
Publication status	Published - Feb 2023

Keywords

C-H activation
D exchange
H
Confinement
Density functional theory calculations
Mechanism
Periodic-DFT
Rhodium
Sigma-alkane complexes

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10.1002/hlca.202200154

Cite this

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title = "Solid-State Confinement Effects in Selective exo-H/D Exchange in the Rhodium σ-Norbornane Complex [(Cy2PCH2CH2PCy2)Rh(η2:η2-C7H12)][BArF4]",

keywords = "C-H activation, D exchange, H, Confinement, Density functional theory calculations, Mechanism, Periodic-DFT, Rhodium, Sigma-alkane complexes",

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AU - Krämer, T

AU - Chadwick, FM

AU - Macgregor, SA

AU - Weller, AS

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KW - D exchange

KW - H

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KW - Density functional theory calculations

KW - Mechanism

KW - Periodic-DFT

KW - Rhodium

KW - Sigma-alkane complexes

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Solid-State Confinement Effects in Selective exo-H/D Exchange in the Rhodium σ-Norbornane Complex [(Cy2PCH2CH2PCy2)Rh(η2:η2-C7H12)][BArF4]

Keywords

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Solid-State Confinement Effects in Selective exo-H/D Exchange in the Rhodium σ-Norbornane Complex [(Cy₂PCH₂CH₂PCy₂)Rh(η²:η²-C₇H₁₂)][BAr^F₄]