Solid-phase synthesis of recyclable diphosphine ligands

Frank Heutz; Michiel Christiaan Samuels; Paul C J Kamer

doi:10.1039/C5CY00287G

Solid-phase synthesis of recyclable diphosphine ligands

Frank Heutz, Michiel Christiaan Samuels, Paul C J Kamer

Research output: Contribution to journal › Article › peer-review

Abstract

An efficient solid-phase synthetic approach towards diphosphine ligands is demonstrated. This modular method offers facile access to this important class of ligands, in quantitative yield, providing huge potential for ligand fine-tuning. These supported ligands can be efficiently applied in asymmetric catalysis. Moreover, the immobilized catalysts can successfully be recycled multiple times addressing several synthetic and work-up challenges in the field of catalytic chemistry.

Original language	English
Pages (from-to)	3296-3301
Journal	Catalysis Science & Technology
Volume	5
Issue number	6
Early online date	17 Apr 2015
DOIs	https://doi.org/10.1039/C5CY00287G
Publication status	Published - 1 Jun 2015

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10.1039/C5CY00287G

Kamer_2015_CST_Solid_AM
© 2015 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C5CY00287G
Accepted author manuscript, 777 KB
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Cite this

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title = "Solid-phase synthesis of recyclable diphosphine ligands",

abstract = "An efficient solid-phase synthetic approach towards diphosphine ligands is demonstrated. This modular method offers facile access to this important class of ligands, in quantitative yield, providing huge potential for ligand fine-tuning. These supported ligands can be efficiently applied in asymmetric catalysis. Moreover, the immobilized catalysts can successfully be recycled multiple times addressing several synthetic and work-up challenges in the field of catalytic chemistry.",

author = "Frank Heutz and Samuels, \{Michiel Christiaan\} and Kamer, \{Paul C J\}",

note = "The authors thank the European Union (Marie Curie ITN SusPhos, Grant Agreement No. 317404 and COST action PhoSciNet cm08602) for financial support. ",

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N2 - An efficient solid-phase synthetic approach towards diphosphine ligands is demonstrated. This modular method offers facile access to this important class of ligands, in quantitative yield, providing huge potential for ligand fine-tuning. These supported ligands can be efficiently applied in asymmetric catalysis. Moreover, the immobilized catalysts can successfully be recycled multiple times addressing several synthetic and work-up challenges in the field of catalytic chemistry.

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Solid-phase synthesis of recyclable diphosphine ligands

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Marie Curie SusPhos: A European Trainging Network for Sustainable Phosphorus Chemistry

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Solid-phase synthesis of recyclable diphosphine ligands

Abstract

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Marie Curie SusPhos: A European Trainging Network for Sustainable Phosphorus Chemistry

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