Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s

Guoxiong Hua; J. Derek Woollins

doi:10.1016/j.poly.2012.05.010

Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s

Guoxiong Hua, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of sodium alkoxides [(RONa)-O-1, R-1 = CH3, CH3CH2, (CH3)(2)CH and CH3CH2CH2] with 2,4-diphenyl-1,3-diselenadiphosphetane-2,4-diselenide [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) gave the non-symmetric sodium phenyldiselenophosphonate salts 1a-1d, the latter were further treated with haloalkanes [(RX)-X-2, R-2 = alkyl and aryl; X = Br, Cl and I] or dihaloalkanes [Br-(CH2)(n)-Br, n = 1-3 and BrCH2C6H4CH2Br-p] to afford a series of new Se-alkyl O-alkylphenylphosphonodiselenoate esters 2a-2k and Se,Se'-dialkyl-O,O'-dialkyl bis(phenylphosphonodiselenoate) esters 3a-3j in good to excellent yields. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	190-195
Number of pages	6
Journal	Polyhedron
Volume	42
Issue number	1
DOIs	https://doi.org/10.1016/j.poly.2012.05.010
Publication status	Published - 25 Jul 2012

Keywords

Woollins’ reagent
Phosphorus
Selenium
Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl
bis(phenylphosphonodiselenoate) esters

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10.1016/j.poly.2012.05.010

hua2012polyhedron190
© 2012 Published by Elsevier Ltd. All rights reserved. This is the author’s version of a work that was accepted for publication in Polyhedron. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Polyhedron, 42, 1, 25 July 2012 DOI 10.1016/j.poly.2012.05.010
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title = "Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s",

abstract = "The reaction of sodium alkoxides [(RONa)-O-1, R-1 = CH3, CH3CH2, (CH3)(2)CH and CH3CH2CH2] with 2,4-diphenyl-1,3-diselenadiphosphetane-2,4-diselenide [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) gave the non-symmetric sodium phenyldiselenophosphonate salts 1a-1d, the latter were further treated with haloalkanes [(RX)-X-2, R-2 = alkyl and aryl; X = Br, Cl and I] or dihaloalkanes [Br-(CH2)(n)-Br, n = 1-3 and BrCH2C6H4CH2Br-p] to afford a series of new Se-alkyl O-alkylphenylphosphonodiselenoate esters 2a-2k and Se,Se'-dialkyl-O,O'-dialkyl bis(phenylphosphonodiselenoate) esters 3a-3j in good to excellent yields. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved.",

keywords = "Woollins{\textquoteright} reagent, Phosphorus, Selenium, Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl, bis(phenylphosphonodiselenoate) esters",

author = "Guoxiong Hua and Woollins, {J. Derek}",

note = "Funding: University of St Andrews",

year = "2012",

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doi = "10.1016/j.poly.2012.05.010",

language = "English",

volume = "42",

pages = "190--195",

journal = "Polyhedron",

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T1 - Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s

AU - Hua, Guoxiong

AU - Woollins, J. Derek

N1 - Funding: University of St Andrews

PY - 2012/7/25

Y1 - 2012/7/25

N2 - The reaction of sodium alkoxides [(RONa)-O-1, R-1 = CH3, CH3CH2, (CH3)(2)CH and CH3CH2CH2] with 2,4-diphenyl-1,3-diselenadiphosphetane-2,4-diselenide [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) gave the non-symmetric sodium phenyldiselenophosphonate salts 1a-1d, the latter were further treated with haloalkanes [(RX)-X-2, R-2 = alkyl and aryl; X = Br, Cl and I] or dihaloalkanes [Br-(CH2)(n)-Br, n = 1-3 and BrCH2C6H4CH2Br-p] to afford a series of new Se-alkyl O-alkylphenylphosphonodiselenoate esters 2a-2k and Se,Se'-dialkyl-O,O'-dialkyl bis(phenylphosphonodiselenoate) esters 3a-3j in good to excellent yields. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved.

AB - The reaction of sodium alkoxides [(RONa)-O-1, R-1 = CH3, CH3CH2, (CH3)(2)CH and CH3CH2CH2] with 2,4-diphenyl-1,3-diselenadiphosphetane-2,4-diselenide [PhP(Se)(mu-Se)](2) (Woollins' reagent, WR) gave the non-symmetric sodium phenyldiselenophosphonate salts 1a-1d, the latter were further treated with haloalkanes [(RX)-X-2, R-2 = alkyl and aryl; X = Br, Cl and I] or dihaloalkanes [Br-(CH2)(n)-Br, n = 1-3 and BrCH2C6H4CH2Br-p] to afford a series of new Se-alkyl O-alkylphenylphosphonodiselenoate esters 2a-2k and Se,Se'-dialkyl-O,O'-dialkyl bis(phenylphosphonodiselenoate) esters 3a-3j in good to excellent yields. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved.

KW - Woollins’ reagent

KW - Phosphorus

KW - Selenium

KW - Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl

KW - bis(phenylphosphonodiselenoate) esters

U2 - 10.1016/j.poly.2012.05.010

DO - 10.1016/j.poly.2012.05.010

M3 - Article

SN - 0277-5387

VL - 42

SP - 190

EP - 195

JO - Polyhedron

JF - Polyhedron

IS - 1

ER -

Sodium phenyldiselenophosphonate salts and Se-alkyl-O-alkylphenyl-phosphonodiselenoates and Se,Se '-dialkyl-O,O '-dialkyl-bis(phenylphosphonodiselenoate)s

Abstract

Keywords

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