Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

Andreas Nordheider, Kasun Sankalpa Athukorala Arachchige, Alexandra Martha Zoya Slawin, J Derek Woollins, Tristram Chivers

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11 Citations (Scopus)
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Abstract

Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.

Original languageEnglish
Pages (from-to)8781-8783
JournalDalton Transactions
Volume44
Issue number19
Early online date6 Jan 2015
DOIs
Publication statusPublished - 21 May 2015

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