Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

Andreas Nordheider; Kasun Sankalpa Athukorala Arachchige; Alexandra Martha Zoya Slawin; J Derek Woollins; Tristram  Chivers

doi:10.1039/C4DT03257H

Sodium and rhodium complexes of a spirocyclic Te₅ dianion supported by P₂N₂ rings

Andreas Nordheider, Kasun Sankalpa Athukorala Arachchige, Alexandra Martha Zoya Slawin, J Derek Woollins, Tristram Chivers

Research output: Contribution to journal › Article › peer-review

Abstract

Reactions of the dianion [Te(^tBuN)P(μ-NtBu)2P(N^tBu)Te]²⁻ with I2 or [Cp*RhCl₂]₂ unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{^tBuN(Te)P(μ-N^tBu)₂P(Te)N^tBu}2μ-Te]²⁻, which is N,N′-coordinated to two Na⁺ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.

Original language	English
Pages (from-to)	8781-8783
Journal	Dalton Transactions
Volume	44
Issue number	19
Early online date	6 Jan 2015
DOIs	https://doi.org/10.1039/C4DT03257H
Publication status	Published - 21 May 2015

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10.1039/C4DT03257H

Woollins_2014_DT_Sodium
© Royal Society of Chemistry 2015. This work may not be further copied or distributed. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4DT03257H
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title = "Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings",

abstract = "Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.",

author = "Andreas Nordheider and {Athukorala Arachchige}, {Kasun Sankalpa} and Slawin, {Alexandra Martha Zoya} and Woollins, {J Derek} and Tristram Chivers",

note = "The authors thank EPSRC and NSERC (Canada) for financial support. ",

year = "2015",

month = may,

day = "21",

doi = "10.1039/C4DT03257H",

language = "English",

volume = "44",

pages = "8781--8783",

journal = "Dalton Transactions",

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T1 - Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

AU - Nordheider, Andreas

AU - Athukorala Arachchige, Kasun Sankalpa

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, J Derek

AU - Chivers, Tristram

N1 - The authors thank EPSRC and NSERC (Canada) for financial support.

PY - 2015/5/21

Y1 - 2015/5/21

N2 - Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.

AB - Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.

UR - http://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h1.pdf

UR - http://www.rsc.org/suppdata/dt/c4/c4dt03257h/c4dt03257h2.cif

U2 - 10.1039/C4DT03257H

DO - 10.1039/C4DT03257H

M3 - Article

SN - 1477-9226

VL - 44

SP - 8781

EP - 8783

JO - Dalton Transactions

JF - Dalton Transactions

IS - 19

ER -

Sodium and rhodium complexes of a spirocyclic Te₅ dianion supported by P₂N₂ rings

Abstract

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