Simple synthetic routes to ruthenium-indenylidene olefin metathesis catalysts

César Alejandro Urbina Blanco; Simone Manzini; Jessica Perez Gomes; Angelino Doppiu; Steven Patrick Nolan

doi:10.1039/c1cc10741k

Simple synthetic routes to ruthenium-indenylidene olefin metathesis catalysts

César Alejandro Urbina Blanco, Simone Manzini, Jessica Perez Gomes, Angelino Doppiu, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

An efficient synthetic protocol involving reactions between the
free carbene and [RuCl2(PPh3)2(Ind)] followed by addition of
pyridine leads to the isolation of olefin metathesis active
[RuCl2(L)(Py)(Ind)] (L=SIMes and SIPr) complexes. This novel
approach circumvents the use of costly tricyclohexylphosphine.

Original language	English
Journal	Chemical Communications
Early online date	21 Mar 2011
DOIs	https://doi.org/10.1039/c1cc10741k
Publication status	Published - 2011

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title = "Simple synthetic routes to ruthenium-indenylidene olefin metathesis catalysts",

abstract = "An efficient synthetic protocol involving reactions between the free carbene and [RuCl2(PPh3)2(Ind)] followed by addition of pyridine leads to the isolation of olefin metathesis active [RuCl2(L)(Py)(Ind)] (L=SIMes and SIPr) complexes. This novel approach circumvents the use of costly tricyclohexylphosphine.",

author = "\{Urbina Blanco\}, \{C{\'e}sar Alejandro\} and Simone Manzini and \{Perez Gomes\}, Jessica and Angelino Doppiu and Nolan, \{Steven Patrick\}",

year = "2011",

doi = "10.1039/c1cc10741k",

language = "English",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Simple synthetic routes to ruthenium-indenylidene olefin metathesis catalysts

AU - Urbina Blanco, César Alejandro

AU - Manzini, Simone

AU - Perez Gomes, Jessica

AU - Doppiu, Angelino

AU - Nolan, Steven Patrick

PY - 2011

Y1 - 2011

N2 - An efficient synthetic protocol involving reactions between the free carbene and [RuCl2(PPh3)2(Ind)] followed by addition of pyridine leads to the isolation of olefin metathesis active [RuCl2(L)(Py)(Ind)] (L=SIMes and SIPr) complexes. This novel approach circumvents the use of costly tricyclohexylphosphine.

AB - An efficient synthetic protocol involving reactions between the free carbene and [RuCl2(PPh3)2(Ind)] followed by addition of pyridine leads to the isolation of olefin metathesis active [RuCl2(L)(Py)(Ind)] (L=SIMes and SIPr) complexes. This novel approach circumvents the use of costly tricyclohexylphosphine.

UR - https://www.scopus.com/pages/publications/79954430509

U2 - 10.1039/c1cc10741k

DO - 10.1039/c1cc10741k

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Simple synthetic routes to ruthenium-indenylidene olefin metathesis catalysts

Abstract

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