Silver(I) coordination polymers using thioether macrocycle building blocks

AJ Blake; NR Champness; SM Howdle; PB Webb

doi:10.1021/ic991145d

Silver(I) coordination polymers using thioether macrocycle building blocks

AJ Blake
, NR Champness^*
, SM Howdle
, PB Webb

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

[Ag-2(hfpd)(2)([14]aneS(4))(infinity), and [Ag(hfpd)([9]aneS(3))(infinity), form one-dimensional coordination polymers in which the polymeric nature of the complexes is generated by one of the thioether donors adopting unusual bridging modes to link metal centers. The strongly coordinating hfpd anions act to inhibit polymer propagation.

Original language	English
Pages (from-to)	1035-+
Number of pages	5
Journal	Inorganic Chemistry
Volume	39
Issue number	5
DOIs	https://doi.org/10.1021/ic991145d
Publication status	Published - 6 Mar 2000

Keywords

CRYSTAL-STRUCTURES
COMPLEXES
NETWORKS
CHEMISTRY
COPPER(I)
CONFORMATION
DITHIOETHER
COUNTERION
PYRAZINE
CATIONS

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title = "Silver(I) coordination polymers using thioether macrocycle building blocks",

abstract = "[Ag-2(hfpd)(2)([14]aneS(4))(infinity), and [Ag(hfpd)([9]aneS(3))(infinity), form one-dimensional coordination polymers in which the polymeric nature of the complexes is generated by one of the thioether donors adopting unusual bridging modes to link metal centers. The strongly coordinating hfpd anions act to inhibit polymer propagation.",

keywords = "CRYSTAL-STRUCTURES, COMPLEXES, NETWORKS, CHEMISTRY, COPPER(I), CONFORMATION, DITHIOETHER, COUNTERION, PYRAZINE, CATIONS",

author = "AJ Blake and NR Champness and SM Howdle and PB Webb",

year = "2000",

month = mar,

day = "6",

doi = "10.1021/ic991145d",

language = "English",

volume = "39",

pages = "1035--+",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society (ACS)",

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TY - JOUR

T1 - Silver(I) coordination polymers using thioether macrocycle building blocks

AU - Blake, AJ

AU - Champness, NR

AU - Howdle, SM

AU - Webb, PB

PY - 2000/3/6

Y1 - 2000/3/6

N2 - [Ag-2(hfpd)(2)([14]aneS(4))(infinity), and [Ag(hfpd)([9]aneS(3))(infinity), form one-dimensional coordination polymers in which the polymeric nature of the complexes is generated by one of the thioether donors adopting unusual bridging modes to link metal centers. The strongly coordinating hfpd anions act to inhibit polymer propagation.

AB - [Ag-2(hfpd)(2)([14]aneS(4))(infinity), and [Ag(hfpd)([9]aneS(3))(infinity), form one-dimensional coordination polymers in which the polymeric nature of the complexes is generated by one of the thioether donors adopting unusual bridging modes to link metal centers. The strongly coordinating hfpd anions act to inhibit polymer propagation.

KW - CRYSTAL-STRUCTURES

KW - COMPLEXES

KW - NETWORKS

KW - CHEMISTRY

KW - COPPER(I)

KW - CONFORMATION

KW - DITHIOETHER

KW - COUNTERION

KW - PYRAZINE

KW - CATIONS

U2 - 10.1021/ic991145d

DO - 10.1021/ic991145d

M3 - Article

SN - 0020-1669

VL - 39

SP - 1035-+

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 5

ER -

Silver(I) coordination polymers using thioether macrocycle building blocks

Abstract

Keywords

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