Silver(I) coordination polymers using thioether macrocycle building blocks

AJ Blake, NR Champness*, SM Howdle, PB Webb

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

42 Citations (Scopus)

Abstract

[Ag-2(hfpd)(2)([14]aneS(4))(infinity), and [Ag(hfpd)([9]aneS(3))(infinity), form one-dimensional coordination polymers in which the polymeric nature of the complexes is generated by one of the thioether donors adopting unusual bridging modes to link metal centers. The strongly coordinating hfpd anions act to inhibit polymer propagation.

Original languageEnglish
Pages (from-to)1035-+
Number of pages5
JournalInorganic Chemistry
Volume39
Issue number5
DOIs
Publication statusPublished - 6 Mar 2000

Keywords

  • CRYSTAL-STRUCTURES
  • COMPLEXES
  • NETWORKS
  • CHEMISTRY
  • COPPER(I)
  • CONFORMATION
  • DITHIOETHER
  • COUNTERION
  • PYRAZINE
  • CATIONS

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