Separation studies in a continuous flow fluorous biphasic system - Proof of concept

E  Perperi; Y L  Huang; P  Angeli; G  Manos; D J  Cole-Hamilton

doi:10.1016/j.molcata.2004.05.038

Separation studies in a continuous flow fluorous biphasic system - Proof of concept

E Perperi, Y L Huang, P Angeli, G Manos, D J Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A proof of concept study was undertaken for the separation of the fluorous solvent from the organic reactants/products of a fluorous biphasic system, in the absence of fluorous modified Rh catalyst. Fast and efficient separation of the two phases was observed. The more polar products were present in the organic phase-i.e. the higher the simulated conversion level-the less was the leaching of the fluorous solvent in the organic phase. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	19-27
Number of pages	9
Journal	Journal of Molecular Catalysis A: Chemical
Volume	221
DOIs	https://doi.org/10.1016/j.molcata.2004.05.038
Publication status	Published - 1 Nov 2004

Keywords

liquid-liquid separation
octene
phase behaviour
fluorous biphasic system
hydroformylation
CATALYST SEPARATION
HOMOGENEOUS CATALYSIS
HYDROFORMYLATION
OLEFINS
MICROEMULSION
CHEMISTRY

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10.1016/j.molcata.2004.05.038

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title = "Separation studies in a continuous flow fluorous biphasic system - Proof of concept",

abstract = "A proof of concept study was undertaken for the separation of the fluorous solvent from the organic reactants/products of a fluorous biphasic system, in the absence of fluorous modified Rh catalyst. Fast and efficient separation of the two phases was observed. The more polar products were present in the organic phase-i.e. the higher the simulated conversion level-the less was the leaching of the fluorous solvent in the organic phase. (C) 2004 Elsevier B.V. All rights reserved.",

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author = "E Perperi and Huang, {Y L} and P Angeli and G Manos and Cole-Hamilton, {D J}",

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AU - Perperi, E

AU - Huang, Y L

AU - Angeli, P

AU - Manos, G

AU - Cole-Hamilton, D J

PY - 2004/11/1

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N2 - A proof of concept study was undertaken for the separation of the fluorous solvent from the organic reactants/products of a fluorous biphasic system, in the absence of fluorous modified Rh catalyst. Fast and efficient separation of the two phases was observed. The more polar products were present in the organic phase-i.e. the higher the simulated conversion level-the less was the leaching of the fluorous solvent in the organic phase. (C) 2004 Elsevier B.V. All rights reserved.

AB - A proof of concept study was undertaken for the separation of the fluorous solvent from the organic reactants/products of a fluorous biphasic system, in the absence of fluorous modified Rh catalyst. Fast and efficient separation of the two phases was observed. The more polar products were present in the organic phase-i.e. the higher the simulated conversion level-the less was the leaching of the fluorous solvent in the organic phase. (C) 2004 Elsevier B.V. All rights reserved.

KW - liquid-liquid separation

KW - octene

KW - phase behaviour

KW - fluorous biphasic system

KW - hydroformylation

KW - CATALYST SEPARATION

KW - HOMOGENEOUS CATALYSIS

KW - HYDROFORMYLATION

KW - OLEFINS

KW - MICROEMULSION

KW - CHEMISTRY

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DO - 10.1016/j.molcata.2004.05.038

M3 - Article

VL - 221

SP - 19

EP - 27

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

ER -

Separation studies in a continuous flow fluorous biphasic system - Proof of concept

Abstract

Keywords

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