Separation and identification of halocycloalkanes by gas chromatography. Part II

D. S. Ashton; J. M. Tedder; J. C. Walton

doi:10.1016/S0021-9673(00)89510-2

Separation and identification of halocycloalkanes by gas chromatography. Part II

D. S. Ashton^*, J. M. Tedder, J. C. Walton

^*Corresponding author for this work

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Abstract

Mixtures of isomeric dihalo- and halomethylcyclopentanes and of dihalo-, halo-methyl- and halocyanocyclobutanes have been separated by gas chromatography on a tritolylphosphate column. The order of elution is the same for each set of isomeric disubstituted cycloalkanes. The relative retention volumes can be used to determine rapidly the structure of a given isomer and distringuish it from other stereoisomers. An attempt is made to rationalise the retention volume data in terms of the structural properties of the cycloalkanes.

Original language	English
Pages (from-to)	269-274
Number of pages	6
Journal	Journal of Chromatography A
Volume	72
Issue number	2
DOIs	https://doi.org/10.1016/S0021-9673(00)89510-2
Publication status	Published - 18 Oct 1972

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abstract = "Mixtures of isomeric dihalo- and halomethylcyclopentanes and of dihalo-, halo-methyl- and halocyanocyclobutanes have been separated by gas chromatography on a tritolylphosphate column. The order of elution is the same for each set of isomeric disubstituted cycloalkanes. The relative retention volumes can be used to determine rapidly the structure of a given isomer and distringuish it from other stereoisomers. An attempt is made to rationalise the retention volume data in terms of the structural properties of the cycloalkanes.",

author = "Ashton, \{D. S.\} and Tedder, \{J. M.\} and Walton, \{J. C.\}",

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AU - Tedder, J. M.

AU - Walton, J. C.

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N2 - Mixtures of isomeric dihalo- and halomethylcyclopentanes and of dihalo-, halo-methyl- and halocyanocyclobutanes have been separated by gas chromatography on a tritolylphosphate column. The order of elution is the same for each set of isomeric disubstituted cycloalkanes. The relative retention volumes can be used to determine rapidly the structure of a given isomer and distringuish it from other stereoisomers. An attempt is made to rationalise the retention volume data in terms of the structural properties of the cycloalkanes.

AB - Mixtures of isomeric dihalo- and halomethylcyclopentanes and of dihalo-, halo-methyl- and halocyanocyclobutanes have been separated by gas chromatography on a tritolylphosphate column. The order of elution is the same for each set of isomeric disubstituted cycloalkanes. The relative retention volumes can be used to determine rapidly the structure of a given isomer and distringuish it from other stereoisomers. An attempt is made to rationalise the retention volume data in terms of the structural properties of the cycloalkanes.

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U2 - 10.1016/S0021-9673(00)89510-2

DO - 10.1016/S0021-9673(00)89510-2

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SP - 269

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IS - 2

ER -

Separation and identification of halocycloalkanes by gas chromatography. Part II

Abstract

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