Separation and identification of halocycloalkanes by gas chromatography. Part II

D. S. Ashton*, J. M. Tedder, J. C. Walton

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Mixtures of isomeric dihalo- and halomethylcyclopentanes and of dihalo-, halo-methyl- and halocyanocyclobutanes have been separated by gas chromatography on a tritolylphosphate column. The order of elution is the same for each set of isomeric disubstituted cycloalkanes. The relative retention volumes can be used to determine rapidly the structure of a given isomer and distringuish it from other stereoisomers. An attempt is made to rationalise the retention volume data in terms of the structural properties of the cycloalkanes.

Original languageEnglish
Pages (from-to)269-274
Number of pages6
JournalJournal of Chromatography A
Volume72
Issue number2
DOIs
Publication statusPublished - 18 Oct 1972

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