Self-templating of large rings by small rings in 4,4 '-bipyridyl-3,4-dihydroxy-3-cyclobutene-1,2-dione (2/3)

E J  MacLean; P S  Wheatley; G  Ferguson; C  Glidewell

doi:10.1107/S010827019900952X

Self-templating of large rings by small rings in 4,4 '-bipyridyl-3,4-dihydroxy-3-cyclobutene-1,2-dione (2/3)

E J MacLean, P S Wheatley, G Ferguson, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound is a salt, bis(4,4'-bipyridyl-4,4'-diium) bis[3,4-dihydroxy-3-cyclobutene-1,2-dionate(1 -)] 3,4-dihydroxy-3-cyclobutene-1,2-dionate( 2C(10)H(10)-N-2(2+) . 2C(4)HO(4)(-). C4O42-. The cations and the (C4O4)(2-) anions are linked by two types of short N-H ... O hydrogen bond [N ... O 2.595(2) and 2.622(2) Angstrom; N-H ... O 167 and 170 degrees] to form a planar rectangular net built from a single type of centrosymmetric R-8(6)(56) ring. The (C4HO4)(-) anions are linked by paired short O-H ... O hydrogen bonds [O ... O 2.471(2)Angstrom and O-H ... O 152 degrees] into centrosymmetric dimers containing an R-2(2)(10) motif. A [(C4HO4)(-)](2) dimer lies at the centre of each R-8(6)(56) ring, and is linked to it by two C-H ... O hydrogen bonds [C ... O 3.318(3) and 3.165 (3) Angstrom; C-H ... O 155 and 151 degrees].

Original language	English
Pages (from-to)	1892-1896
Number of pages	5
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Issue number	11
DOIs	https://doi.org/10.1107/S010827019900952X
Publication status	Published - 15 Nov 1999

Keywords

CENTER-DOT-O
CRYSTAL

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@article{fe4773aeee154e6c80a757df57eb6883,

title = "Self-templating of large rings by small rings in 4,4 '-bipyridyl-3,4-dihydroxy-3-cyclobutene-1,2-dione (2/3)",

abstract = "The title compound is a salt, bis(4,4'-bipyridyl-4,4'-diium) bis[3,4-dihydroxy-3-cyclobutene-1,2-dionate(1 -)] 3,4-dihydroxy-3-cyclobutene-1,2-dionate( 2C(10)H(10)-N-2(2+) . 2C(4)HO(4)(-). C4O42-. The cations and the (C4O4)(2-) anions are linked by two types of short N-H ... O hydrogen bond [N ... O 2.595(2) and 2.622(2) Angstrom; N-H ... O 167 and 170 degrees] to form a planar rectangular net built from a single type of centrosymmetric R-8(6)(56) ring. The (C4HO4)(-) anions are linked by paired short O-H ... O hydrogen bonds [O ... O 2.471(2)Angstrom and O-H ... O 152 degrees] into centrosymmetric dimers containing an R-2(2)(10) motif. A [(C4HO4)(-)](2) dimer lies at the centre of each R-8(6)(56) ring, and is linked to it by two C-H ... O hydrogen bonds [C ... O 3.318(3) and 3.165 (3) Angstrom; C-H ... O 155 and 151 degrees].",

keywords = "CENTER-DOT-O, CRYSTAL",

author = "MacLean, {E J} and Wheatley, {P S} and G Ferguson and C Glidewell",

year = "1999",

month = nov,

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doi = "10.1107/S010827019900952X",

language = "English",

volume = "55",

pages = "1892--1896",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

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TY - JOUR

T1 - Self-templating of large rings by small rings in 4,4 '-bipyridyl-3,4-dihydroxy-3-cyclobutene-1,2-dione (2/3)

AU - MacLean, E J

AU - Wheatley, P S

AU - Ferguson, G

AU - Glidewell, C

PY - 1999/11/15

Y1 - 1999/11/15

N2 - The title compound is a salt, bis(4,4'-bipyridyl-4,4'-diium) bis[3,4-dihydroxy-3-cyclobutene-1,2-dionate(1 -)] 3,4-dihydroxy-3-cyclobutene-1,2-dionate( 2C(10)H(10)-N-2(2+) . 2C(4)HO(4)(-). C4O42-. The cations and the (C4O4)(2-) anions are linked by two types of short N-H ... O hydrogen bond [N ... O 2.595(2) and 2.622(2) Angstrom; N-H ... O 167 and 170 degrees] to form a planar rectangular net built from a single type of centrosymmetric R-8(6)(56) ring. The (C4HO4)(-) anions are linked by paired short O-H ... O hydrogen bonds [O ... O 2.471(2)Angstrom and O-H ... O 152 degrees] into centrosymmetric dimers containing an R-2(2)(10) motif. A [(C4HO4)(-)](2) dimer lies at the centre of each R-8(6)(56) ring, and is linked to it by two C-H ... O hydrogen bonds [C ... O 3.318(3) and 3.165 (3) Angstrom; C-H ... O 155 and 151 degrees].

AB - The title compound is a salt, bis(4,4'-bipyridyl-4,4'-diium) bis[3,4-dihydroxy-3-cyclobutene-1,2-dionate(1 -)] 3,4-dihydroxy-3-cyclobutene-1,2-dionate( 2C(10)H(10)-N-2(2+) . 2C(4)HO(4)(-). C4O42-. The cations and the (C4O4)(2-) anions are linked by two types of short N-H ... O hydrogen bond [N ... O 2.595(2) and 2.622(2) Angstrom; N-H ... O 167 and 170 degrees] to form a planar rectangular net built from a single type of centrosymmetric R-8(6)(56) ring. The (C4HO4)(-) anions are linked by paired short O-H ... O hydrogen bonds [O ... O 2.471(2)Angstrom and O-H ... O 152 degrees] into centrosymmetric dimers containing an R-2(2)(10) motif. A [(C4HO4)(-)](2) dimer lies at the centre of each R-8(6)(56) ring, and is linked to it by two C-H ... O hydrogen bonds [C ... O 3.318(3) and 3.165 (3) Angstrom; C-H ... O 155 and 151 degrees].

KW - CENTER-DOT-O

KW - CRYSTAL

UR - http://www.scopus.com/inward/record.url?scp=0000010949&partnerID=8YFLogxK

U2 - 10.1107/S010827019900952X

DO - 10.1107/S010827019900952X

M3 - Article

SN - 0108-2701

VL - 55

SP - 1892

EP - 1896

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

Self-templating of large rings by small rings in 4,4 '-bipyridyl-3,4-dihydroxy-3-cyclobutene-1,2-dione (2/3)

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