Self-assembly between 1,4-diazabicyclo[2.2.2]octane and bis(hexafluoroalcohols): solid/liquid phase switching for catalyst recycling

Julien Legros; Daniele Bonnet-Delpon; Benoit Crousse; Alexandra M. Z. Slawin

doi:10.1039/c2cy00528j

Self-assembly between 1,4-diazabicyclo[2.2.2]octane and bis(hexafluoroalcohols): solid/liquid phase switching for catalyst recycling

Julien Legros, Daniele Bonnet-Delpon, Benoit Crousse, Alexandra M. Z. Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

Bis(hexafluoroalcohol) derivatives readily self-assemble with 1,4-diazabicyclo[2.2.2]octane through hydrogen bonding. The DABCO (R) catalysts can be released from these crystalline adducts to promote organic transformations. Regeneration of H-bonds allows facile recovery and reuse of this "supramolecular supported catalyst'' (> 10 times).

Original language	English
Pages (from-to)	934-936
Number of pages	3
Journal	Catalysis Science & Technology
Volume	2
Issue number	5
DOIs	https://doi.org/10.1039/c2cy00528j
Publication status	Published - 2012

Access to Document

10.1039/c2cy00528j

Cite this

@article{bd16da1c6e5b4624be1b186e7070e020,

title = "Self-assembly between 1,4-diazabicyclo[2.2.2]octane and bis(hexafluoroalcohols): solid/liquid phase switching for catalyst recycling",

abstract = "Bis(hexafluoroalcohol) derivatives readily self-assemble with 1,4-diazabicyclo[2.2.2]octane through hydrogen bonding. The DABCO (R) catalysts can be released from these crystalline adducts to promote organic transformations. Regeneration of H-bonds allows facile recovery and reuse of this {"}supramolecular supported catalyst'' (> 10 times).",

author = "Julien Legros and Daniele Bonnet-Delpon and Benoit Crousse and Slawin, {Alexandra M. Z.}",

year = "2012",

doi = "10.1039/c2cy00528j",

language = "English",

volume = "2",

pages = "934--936",

journal = "Catalysis Science & Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Self-assembly between 1,4-diazabicyclo[2.2.2]octane and bis(hexafluoroalcohols): solid/liquid phase switching for catalyst recycling

AU - Legros, Julien

AU - Bonnet-Delpon, Daniele

AU - Crousse, Benoit

AU - Slawin, Alexandra M. Z.

PY - 2012

Y1 - 2012

N2 - Bis(hexafluoroalcohol) derivatives readily self-assemble with 1,4-diazabicyclo[2.2.2]octane through hydrogen bonding. The DABCO (R) catalysts can be released from these crystalline adducts to promote organic transformations. Regeneration of H-bonds allows facile recovery and reuse of this "supramolecular supported catalyst'' (> 10 times).

AB - Bis(hexafluoroalcohol) derivatives readily self-assemble with 1,4-diazabicyclo[2.2.2]octane through hydrogen bonding. The DABCO (R) catalysts can be released from these crystalline adducts to promote organic transformations. Regeneration of H-bonds allows facile recovery and reuse of this "supramolecular supported catalyst'' (> 10 times).

U2 - 10.1039/c2cy00528j

DO - 10.1039/c2cy00528j

M3 - Article

SN - 2044-4753

VL - 2

SP - 934

EP - 936

JO - Catalysis Science & Technology

JF - Catalysis Science & Technology

IS - 5

ER -

Self-assembly between 1,4-diazabicyclo[2.2.2]octane and bis(hexafluoroalcohols): solid/liquid phase switching for catalyst recycling

Abstract

Access to Document

Fingerprint

Cite this