Self-assembled hydrogen-bonded bilayers in 1,4-diazabicyclo[2.2.2]octane-N-(phosphonomethyl)imino-diacetic acid-water (1/1/1.5)

K F  Bowes; G  Ferguson; C  Glidewell; A J  Lough

doi:10.1107/S0108270102010648

Self-assembled hydrogen-bonded bilayers in 1,4-diazabicyclo[2.2.2]octane-N-(phosphonomethyl)imino-diacetic acid-water (1/1/1.5)

K F Bowes, G Ferguson, C Glidewell, A J Lough

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound is a hydrated salt, 1,4-diazoniabicyclo[2.2.2]octane-N-[(hydroxyphosphinato)methyl]iminiodiacetate-water (1/1/1.5), C6H14N22+.C5H8NO7P2-.1.5H(2)O, in which one of the water molecules lies across a twofold rotation axis in space group P2/n. The ionic components are linked into sheets by a combination of a three-centre N-H...(O)(2) hydrogen bond and two-centre O-H...O and N-H...O hydrogen bonds, and these sheets are pairwise linked by the water molecules into bilayers, by means of further O-H...O hydrogen bonds.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	58
DOIs	https://doi.org/10.1107/S0108270102010648
Publication status	Published - Aug 2002

Keywords

SUPRAMOLECULAR CHEMISTRY
PHENYLPHOSPHONIC ACID
BUILDING-BLOCK
FRAMEWORK

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@article{a7185adfd4f247a586b11e1bf5701d12,

title = "Self-assembled hydrogen-bonded bilayers in 1,4-diazabicyclo[2.2.2]octane-N-(phosphonomethyl)imino-diacetic acid-water (1/1/1.5)",

abstract = "The title compound is a hydrated salt, 1,4-diazoniabicyclo[2.2.2]octane-N-[(hydroxyphosphinato)methyl]iminiodiacetate-water (1/1/1.5), C6H14N22+.C5H8NO7P2-.1.5H(2)O, in which one of the water molecules lies across a twofold rotation axis in space group P2/n. The ionic components are linked into sheets by a combination of a three-centre N-H...(O)(2) hydrogen bond and two-centre O-H...O and N-H...O hydrogen bonds, and these sheets are pairwise linked by the water molecules into bilayers, by means of further O-H...O hydrogen bonds.",

keywords = "SUPRAMOLECULAR CHEMISTRY, PHENYLPHOSPHONIC ACID, BUILDING-BLOCK, FRAMEWORK",

author = "Bowes, {K F} and G Ferguson and C Glidewell and Lough, {A J}",

year = "2002",

month = aug,

doi = "10.1107/S0108270102010648",

language = "English",

volume = "58",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Self-assembled hydrogen-bonded bilayers in 1,4-diazabicyclo[2.2.2]octane-N-(phosphonomethyl)imino-diacetic acid-water (1/1/1.5)

AU - Bowes, K F

AU - Ferguson, G

AU - Glidewell, C

AU - Lough, A J

PY - 2002/8

Y1 - 2002/8

N2 - The title compound is a hydrated salt, 1,4-diazoniabicyclo[2.2.2]octane-N-[(hydroxyphosphinato)methyl]iminiodiacetate-water (1/1/1.5), C6H14N22+.C5H8NO7P2-.1.5H(2)O, in which one of the water molecules lies across a twofold rotation axis in space group P2/n. The ionic components are linked into sheets by a combination of a three-centre N-H...(O)(2) hydrogen bond and two-centre O-H...O and N-H...O hydrogen bonds, and these sheets are pairwise linked by the water molecules into bilayers, by means of further O-H...O hydrogen bonds.

AB - The title compound is a hydrated salt, 1,4-diazoniabicyclo[2.2.2]octane-N-[(hydroxyphosphinato)methyl]iminiodiacetate-water (1/1/1.5), C6H14N22+.C5H8NO7P2-.1.5H(2)O, in which one of the water molecules lies across a twofold rotation axis in space group P2/n. The ionic components are linked into sheets by a combination of a three-centre N-H...(O)(2) hydrogen bond and two-centre O-H...O and N-H...O hydrogen bonds, and these sheets are pairwise linked by the water molecules into bilayers, by means of further O-H...O hydrogen bonds.

KW - SUPRAMOLECULAR CHEMISTRY

KW - PHENYLPHOSPHONIC ACID

KW - BUILDING-BLOCK

KW - FRAMEWORK

U2 - 10.1107/S0108270102010648

DO - 10.1107/S0108270102010648

M3 - Article

SN - 1600-5759

VL - 58

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Self-assembled hydrogen-bonded bilayers in 1,4-diazabicyclo[2.2.2]octane-N-(phosphonomethyl)imino-diacetic acid-water (1/1/1.5)

Abstract

Keywords

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