Selective formation of pentan-3-one from carbon monoxide and ethene in methanol

RAM Robertson; AD Poole; MJ Payne; David John Cole-Hamilton

doi:10.1039/b002629h

Selective formation of pentan-3-one from carbon monoxide and ethene in methanol

RAM Robertson, AD Poole, MJ Payne, David John Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

In the presence of rhodium complexes of triethylphosphine, CO and ethene react in methanol to give pentan-3-one with selectivities up to 85%; model studies and deuterium labelling suggest that the mechanism involves hydroxycarbene and eta(2)-3-oxopentyl derivatives.

Original language	English
Pages (from-to)	1817-1819
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/b002629h
Publication status	Published - 2000

Keywords

HYDROCARBONYLATION
COMPLEXES
ETHYLENE
ALCOHOLS
ALKENES

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10.1039/b002629h

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@article{03834cefaf3242eb88497089f680cce2,

title = "Selective formation of pentan-3-one from carbon monoxide and ethene in methanol",

abstract = "In the presence of rhodium complexes of triethylphosphine, CO and ethene react in methanol to give pentan-3-one with selectivities up to 85\%; model studies and deuterium labelling suggest that the mechanism involves hydroxycarbene and eta(2)-3-oxopentyl derivatives.",

keywords = "HYDROCARBONYLATION, COMPLEXES, ETHYLENE, ALCOHOLS, ALKENES",

author = "RAM Robertson and AD Poole and MJ Payne and Cole-Hamilton, \{David John\}",

year = "2000",

doi = "10.1039/b002629h",

language = "English",

pages = "1817--1819",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "12",

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TY - JOUR

T1 - Selective formation of pentan-3-one from carbon monoxide and ethene in methanol

AU - Robertson, RAM

AU - Poole, AD

AU - Payne, MJ

AU - Cole-Hamilton, David John

PY - 2000

Y1 - 2000

N2 - In the presence of rhodium complexes of triethylphosphine, CO and ethene react in methanol to give pentan-3-one with selectivities up to 85%; model studies and deuterium labelling suggest that the mechanism involves hydroxycarbene and eta(2)-3-oxopentyl derivatives.

AB - In the presence of rhodium complexes of triethylphosphine, CO and ethene react in methanol to give pentan-3-one with selectivities up to 85%; model studies and deuterium labelling suggest that the mechanism involves hydroxycarbene and eta(2)-3-oxopentyl derivatives.

KW - HYDROCARBONYLATION

KW - COMPLEXES

KW - ETHYLENE

KW - ALCOHOLS

KW - ALKENES

UR - https://www.scopus.com/pages/publications/0002689468

U2 - 10.1039/b002629h

DO - 10.1039/b002629h

M3 - Article

SN - 1470-479X

SP - 1817

EP - 1819

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 12

ER -

Selective formation of pentan-3-one from carbon monoxide and ethene in methanol

Abstract

Keywords

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