Selective depolymerisation of γ-oxidised lignin via NHC catalysed redox esterification

Ganyuan Xiao, Christopher Lancefield, Nicholas James Westwood

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The development of new catalytic methods for the processing of lignocellulose‐derived renewable feedstocks continues to gain momentum, despite the considerable challenges associated with the use of complex biopolymers such as lignin. Here, we report a new two‐step depolymerisation method for lignin involving primary alcohol oxidation followed by a NHC‐mediated redox esterification‐depolymerisation step. The process takes advantage of the inherent structure of the β‐aryl ether units present in the specific type of lignin that was used (butanosolv) and delivers 4 novel aromatic monomers which retain the C3 side chain present in the lignin subunits. The utility of the major product is assessed suggesting that rapid access to a wide range of interesting chemical could be achieved from this renewable building block.
Original languageEnglish
JournalChemCatChem
VolumeEarly View
Early online date11 Jun 2019
DOIs
Publication statusE-pub ahead of print - 11 Jun 2019

Keywords

  • Lignin
  • Oxidation
  • NHC catalysis
  • Biomass conversion
  • Butanol

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