Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor

David R. Alston; Alexandra M.Z. Slawin; J. Fraser Stoddart; David J. Williams; Ryszard Zarzycki

doi:10.1002/anie.198706921

Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor

David R. Alston, Alexandra M.Z. Slawin, J. Fraser Stoddart^*, David J. Williams, Ryszard Zarzycki

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH₃)₄][PF₆]₂ forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH₃ on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)

Original language	English
Pages (from-to)	692-693
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	7
DOIs	https://doi.org/10.1002/anie.198706921
Publication status	Published - 1 Jan 1987

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abstract = "Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH3)4][PF6]2 forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH3 on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)",

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AU - Stoddart, J. Fraser

AU - Williams, David J.

AU - Zarzycki, Ryszard

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N2 - Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH3)4][PF6]2 forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH3 on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)

AB - Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH3)4][PF6]2 forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH3 on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)

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Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor

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