S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction

J N  Low; J  Cobo; H  Insuasty; M  Estrada; E  Cortes; C  Glidewell

doi:10.1107/S0108270104012090

S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction

J N Low, J Cobo, H Insuasty, M Estrada, E Cortes, C Glidewell

School of Chemistry

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Abstract

The title compound, C10H11NOS2, crystallizes with Z' = 2 in space group C2/c. The molecules are linked by two N - H ... S hydrogen bonds [H ... S = 2.60 and 2.62 Angstrom, N ... S = 3.350 (2) and 3.490 (2) Angstrom, and N - H ... S = 143 and 172degrees] into two distinct types of R-2(2)(8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C H ... pi(arene) hydrogen bond links the two types of dimer into chains.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	60
DOIs	https://doi.org/10.1107/S0108270104012090
Publication status	Published - Jul 2004

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Low, J. N., Cobo, J., Insuasty, H., Estrada, M., Cortes, E., & Glidewell, C. (2004). S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction. Acta Crystallographica Section C-Crystal Structure Communications, 60. https://doi.org/10.1107/S0108270104012090

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title = "S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction",

abstract = "The title compound, C10H11NOS2, crystallizes with Z' = 2 in space group C2/c. The molecules are linked by two N - H ... S hydrogen bonds [H ... S = 2.60 and 2.62 Angstrom, N ... S = 3.350 (2) and 3.490 (2) Angstrom, and N - H ... S = 143 and 172degrees] into two distinct types of R-2(2)(8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C H ... pi(arene) hydrogen bond links the two types of dimer into chains.",

author = "Low, \{J N\} and J Cobo and H Insuasty and M Estrada and E Cortes and C Glidewell",

year = "2004",

month = jul,

doi = "10.1107/S0108270104012090",

language = "English",

volume = "60",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

Low, JN, Cobo, J, Insuasty, H, Estrada, M, Cortes, E & Glidewell, C 2004, 'S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction', Acta Crystallographica Section C-Crystal Structure Communications, vol. 60. https://doi.org/10.1107/S0108270104012090

S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction. / Low, J N ; Cobo, J ; Insuasty, H et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 60, 07.2004.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction

AU - Low, J N

AU - Cobo, J

AU - Insuasty, H

AU - Estrada, M

AU - Cortes, E

AU - Glidewell, C

PY - 2004/7

Y1 - 2004/7

N2 - The title compound, C10H11NOS2, crystallizes with Z' = 2 in space group C2/c. The molecules are linked by two N - H ... S hydrogen bonds [H ... S = 2.60 and 2.62 Angstrom, N ... S = 3.350 (2) and 3.490 (2) Angstrom, and N - H ... S = 143 and 172degrees] into two distinct types of R-2(2)(8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C H ... pi(arene) hydrogen bond links the two types of dimer into chains.

AB - The title compound, C10H11NOS2, crystallizes with Z' = 2 in space group C2/c. The molecules are linked by two N - H ... S hydrogen bonds [H ... S = 2.60 and 2.62 Angstrom, N ... S = 3.350 (2) and 3.490 (2) Angstrom, and N - H ... S = 143 and 172degrees] into two distinct types of R-2(2)(8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C H ... pi(arene) hydrogen bond links the two types of dimer into chains.

UR - https://www.scopus.com/pages/publications/3242808917

U2 - 10.1107/S0108270104012090

DO - 10.1107/S0108270104012090

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 60

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R-2(2)(8) dimers of different symmetry linked into chains by a C-H center dot center dot center dot pi(arene) interaction

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