Ruthenium-indenylidene complexes in ring opening metathesis polymerization (ROMP) reactions

Pierre de Fremont; Herve Clavier; Veronique Montembault; Laurent Fontaine; Steven Patrick Nolan

doi:10.1016/j.molcata.2007.11.038

Ruthenium-indenylidene complexes in ring opening metathesis polymerization (ROMP) reactions

Pierre de Fremont, Herve Clavier, Veronique Montembault, Laurent Fontaine, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The ring opening metathesis polymerization (ROMP) of cycloocta- 1,5-diene (COD) is mediated by a series of six well-defined ruthenium-based indenylidene catalysts. The polymerization kinetics are monitored and compared with three generations of Grubbs' catalyst. Moderate control over the polymerizations was observed for both benzylidene and indenylidene-based catalysts. (c) 2007 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	108-113
Number of pages	6
Journal	Journal of Molecular Catalysis A: Chemical
Volume	283
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2007.11.038
Publication status	Published - 18 Mar 2008

Keywords

indenylidene
ruthenium
ring opening metathesis polymerization (ROMP)
IMIDO ALKYLIDENE COMPLEXES
OLEFIN-METATHESIS
CLOSING METATHESIS
ALLENYLIDENE COMPLEXES
FUNCTIONAL MONOMERS
CARBENE COMPLEXES
ACYCLIC OLEFINS
CATALYSTS
EFFICIENT
LIGANDS

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10.1016/j.molcata.2007.11.038

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title = "Ruthenium-indenylidene complexes in ring opening metathesis polymerization (ROMP) reactions",

abstract = "The ring opening metathesis polymerization (ROMP) of cycloocta- 1,5-diene (COD) is mediated by a series of six well-defined ruthenium-based indenylidene catalysts. The polymerization kinetics are monitored and compared with three generations of Grubbs' catalyst. Moderate control over the polymerizations was observed for both benzylidene and indenylidene-based catalysts. (c) 2007 Elsevier B.V. All rights reserved.",

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author = "{de Fremont}, Pierre and Herve Clavier and Veronique Montembault and Laurent Fontaine and Nolan, {Steven Patrick}",

year = "2008",

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doi = "10.1016/j.molcata.2007.11.038",

language = "English",

volume = "283",

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journal = "Journal of Molecular Catalysis A: Chemical",

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TY - JOUR

T1 - Ruthenium-indenylidene complexes in ring opening metathesis polymerization (ROMP) reactions

AU - de Fremont, Pierre

AU - Clavier, Herve

AU - Montembault, Veronique

AU - Fontaine, Laurent

AU - Nolan, Steven Patrick

PY - 2008/3/18

Y1 - 2008/3/18

N2 - The ring opening metathesis polymerization (ROMP) of cycloocta- 1,5-diene (COD) is mediated by a series of six well-defined ruthenium-based indenylidene catalysts. The polymerization kinetics are monitored and compared with three generations of Grubbs' catalyst. Moderate control over the polymerizations was observed for both benzylidene and indenylidene-based catalysts. (c) 2007 Elsevier B.V. All rights reserved.

AB - The ring opening metathesis polymerization (ROMP) of cycloocta- 1,5-diene (COD) is mediated by a series of six well-defined ruthenium-based indenylidene catalysts. The polymerization kinetics are monitored and compared with three generations of Grubbs' catalyst. Moderate control over the polymerizations was observed for both benzylidene and indenylidene-based catalysts. (c) 2007 Elsevier B.V. All rights reserved.

KW - indenylidene

KW - ruthenium

KW - ring opening metathesis polymerization (ROMP)

KW - IMIDO ALKYLIDENE COMPLEXES

KW - OLEFIN-METATHESIS

KW - CLOSING METATHESIS

KW - ALLENYLIDENE COMPLEXES

KW - FUNCTIONAL MONOMERS

KW - CARBENE COMPLEXES

KW - ACYCLIC OLEFINS

KW - CATALYSTS

KW - EFFICIENT

KW - LIGANDS

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U2 - 10.1016/j.molcata.2007.11.038

DO - 10.1016/j.molcata.2007.11.038

M3 - Article

VL - 283

SP - 108

EP - 113

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Ruthenium-indenylidene complexes in ring opening metathesis polymerization (ROMP) reactions

Abstract

Keywords

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