Ruthenium Hydroxide Complexes in the Racemization of Secondary Alcohols

Pierrick Nun; George C. Fortman; Alexandra M. Z. Slawin; Steven P. Nolan

doi:10.1021/om200956r

Ruthenium Hydroxide Complexes in the Racemization of Secondary Alcohols

Pierrick Nun, George C. Fortman, Alexandra M. Z. Slawin, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Two well-defined 16-electron ruthenium hydroxide complexes were prepared and successfully used in the racemization of aromatic and aliphatic secondary alcohols. The intrinsic basicity of these new complexes permits for the exclusion of KO'Bu in the racemization reaction.

Original language	English
Pages (from-to)	6347-6350
Number of pages	4
Journal	Organometallics
Volume	30
Issue number	23
DOIs	https://doi.org/10.1021/om200956r
Publication status	Published - 12 Dec 2011

Keywords

DYNAMIC KINETIC RESOLUTION
AMBIENT-TEMPERATURE
CATALYTIC RACEMIZATION
ENZYMATIC RESOLUTION
NUCLEOPHILIC CARBENE
CHIRAL ALCOHOLS
METAL
AMINES
ENZYMES
BONDS

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10.1021/om200956r

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title = "Ruthenium Hydroxide Complexes in the Racemization of Secondary Alcohols",

abstract = "Two well-defined 16-electron ruthenium hydroxide complexes were prepared and successfully used in the racemization of aromatic and aliphatic secondary alcohols. The intrinsic basicity of these new complexes permits for the exclusion of KO'Bu in the racemization reaction.",

keywords = "DYNAMIC KINETIC RESOLUTION, AMBIENT-TEMPERATURE, CATALYTIC RACEMIZATION, ENZYMATIC RESOLUTION, NUCLEOPHILIC CARBENE, CHIRAL ALCOHOLS, METAL, AMINES, ENZYMES, BONDS",

author = "Pierrick Nun and Fortman, {George C.} and Slawin, {Alexandra M. Z.} and Nolan, {Steven P.}",

year = "2011",

month = dec,

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doi = "10.1021/om200956r",

language = "English",

volume = "30",

pages = "6347--6350",

journal = "Organometallics",

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TY - JOUR

T1 - Ruthenium Hydroxide Complexes in the Racemization of Secondary Alcohols

AU - Nun, Pierrick

AU - Fortman, George C.

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P.

PY - 2011/12/12

Y1 - 2011/12/12

N2 - Two well-defined 16-electron ruthenium hydroxide complexes were prepared and successfully used in the racemization of aromatic and aliphatic secondary alcohols. The intrinsic basicity of these new complexes permits for the exclusion of KO'Bu in the racemization reaction.

AB - Two well-defined 16-electron ruthenium hydroxide complexes were prepared and successfully used in the racemization of aromatic and aliphatic secondary alcohols. The intrinsic basicity of these new complexes permits for the exclusion of KO'Bu in the racemization reaction.

KW - DYNAMIC KINETIC RESOLUTION

KW - AMBIENT-TEMPERATURE

KW - CATALYTIC RACEMIZATION

KW - ENZYMATIC RESOLUTION

KW - NUCLEOPHILIC CARBENE

KW - CHIRAL ALCOHOLS

KW - METAL

KW - AMINES

KW - ENZYMES

KW - BONDS

U2 - 10.1021/om200956r

DO - 10.1021/om200956r

M3 - Article

SN - 0276-7333

VL - 30

SP - 6347

EP - 6350

JO - Organometallics

JF - Organometallics

IS - 23

ER -

Ruthenium Hydroxide Complexes in the Racemization of Secondary Alcohols

Abstract

Keywords

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