Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(mu-Cl)Cl(NHC)](2) complex (NHC = N-heterocyclic carbene)

Olivier Diebolt, Pierre Braunstein, Steven Patrick Nolan, Catherine S.J. Cazin

Research output: Contribution to journalArticlepeer-review

127 Citations (Scopus)

Abstract

A straightforwardly synthesised complex, [Pd(mu-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.

Original languageEnglish
Pages (from-to)3190-3192
Number of pages3
JournalChemical Communications
Issue number27
Early online date12 May 2008
DOIs
Publication statusPublished - 2008

Keywords

  • BUCHWALD-HARTWIG
  • CROSS-COUPLINGS
  • GENERAL-METHOD
  • CATALYST
  • POLYMERIZATION

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