Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(mu-Cl)Cl(NHC)](2) complex (NHC = N-heterocyclic carbene)

Olivier Diebolt; Pierre Braunstein; Steven Patrick Nolan; Catherine S.J. Cazin

doi:10.1039/b804695f

Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(mu-Cl)Cl(NHC)](2) complex (NHC = N-heterocyclic carbene)

Olivier Diebolt, Pierre Braunstein, Steven Patrick Nolan, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

A straightforwardly synthesised complex, [Pd(mu-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.

Original language	English
Pages (from-to)	3190-3192
Number of pages	3
Journal	Chemical Communications
Issue number	27
Early online date	12 May 2008
DOIs	https://doi.org/10.1039/b804695f
Publication status	Published - 2008

Keywords

BUCHWALD-HARTWIG
CROSS-COUPLINGS
GENERAL-METHOD
CATALYST
POLYMERIZATION

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10.1039/b804695f

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abstract = "A straightforwardly synthesised complex, [Pd(mu-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.",

keywords = "BUCHWALD-HARTWIG, CROSS-COUPLINGS, GENERAL-METHOD, CATALYST, POLYMERIZATION",

author = "Olivier Diebolt and Pierre Braunstein and Nolan, {Steven Patrick} and Cazin, {Catherine S.J.}",

year = "2008",

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AU - Diebolt, Olivier

AU - Braunstein, Pierre

AU - Nolan, Steven Patrick

AU - Cazin, Catherine S.J.

PY - 2008

Y1 - 2008

N2 - A straightforwardly synthesised complex, [Pd(mu-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.

AB - A straightforwardly synthesised complex, [Pd(mu-Cl)Cl(NHC)](2) (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki-Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.

KW - BUCHWALD-HARTWIG

KW - CROSS-COUPLINGS

KW - GENERAL-METHOD

KW - CATALYST

KW - POLYMERIZATION

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IS - 27

ER -

Room-temperature activation of aryl chlorides in Suzuki-Miyaura coupling using a [Pd(mu-Cl)Cl(NHC)](2) complex (NHC = N-heterocyclic carbene)

Abstract

Keywords

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